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author:

Ng, Kim Hoong (Ng, Kim Hoong.) [1] | Chen, Kaijuan (Chen, Kaijuan.) [2] | Cheng, Chin Kui (Cheng, Chin Kui.) [3] | Vo, Dai-Viet N. (Vo, Dai-Viet N..) [4]

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EI

Abstract:

Powdered-photocatalysis of organic wastewater is widely investigated, unfortunately not industrially implemented due to its high energy requirement. Interestingly, such issue may be alleviated via the elimination of mechanical stirring required. Core-shell ZnO-based photocatalysts were developed herein, subsequently demonstrated efficient photocatalytic activities in the absence of mechanical stirring. Results show that the developed SiO2-cored ZnO photocatalyst are highly crystalline, while significantly smaller than coreless, pure ZnO due to the multi-point crystallization prompted. Additionally, it is also inherited with considerable buoyancy ability from SiO2-core in the absence of mechanical stirring, concurrently rendered with UV-active properties due to its ZnO-shell. Experimentally, 55% of particles of ZnO_0.0025 (0.0025 mol of ZnO-deposition) were found stably suspended for 60 min in liquid substrate, as opposed to the instant-settling of pure ZnO particles. In term of photocatalytic activity, ZnO_0.01 manifested the best methylene blue (MB) degradation with 150 mL/min of O2-bubbling. 67.63% of MB was degraded with photocatalyst loading of 0.2 g/L after 120 min UV-irradiation, simultaneously recorded the highest pseudo-first order reaction constant of 9.636 × 10−3 min−1. As summary, the auto-suspending photocatalysis conceptualized in current study offers a high possibility in reducing energy requirement for photo-treatment of wastewater, hence advocating its industrialization potential in near future. © 2020 Elsevier B.V.

Keyword:

II-VI semiconductors Irradiation Oxide minerals Photocatalytic activity Photodegradation Silica Silicon Wastewater treatment Zinc oxide

Community:

  • [ 1 ] [Ng, Kim Hoong]College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 2 ] [Ng, Kim Hoong]School of Energy and Chemical Engineering, Xiamen University Malaysia, Selangor Darul Ehsan, 43900, Malaysia
  • [ 3 ] [Chen, Kaijuan]School of Energy and Chemical Engineering, Xiamen University Malaysia, Selangor Darul Ehsan, 43900, Malaysia
  • [ 4 ] [Cheng, Chin Kui]Department of Chemical Engineering, College of Engineering, Khalifa University, P. O. Box 127788, Abu Dhabi, United Arab Emirates
  • [ 5 ] [Vo, Dai-Viet N.]Center of Excellence for Green Energy and Environmental Nanomaterials (CE@GrEEN), Nguyen Tat Thanh University, 300A Nguyen Tat Thanh, District 4, Ho Chi Minh City; 755414, Viet Nam

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Source :

Journal of Hazardous Materials

ISSN: 0304-3894

Year: 2021

Volume: 409

1 4 . 2 2 4

JCR@2021

1 2 . 2 0 0

JCR@2023

ESI HC Threshold:105

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 13

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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