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author:

Zhu, Guocheng (Zhu, Guocheng.) [1] | Chen, Junming (Chen, Junming.) [2] | Zhang, Shanshan (Zhang, Shanshan.) [3] | Zhao, Zilong (Zhao, Zilong.) [4] | Luo, Huihao (Luo, Huihao.) [5] | Hursthouse, Andrew S. (Hursthouse, Andrew S..) [6] | Wan, Peng (Wan, Peng.) [7] | Fan, Gongduan (Fan, Gongduan.) [8] (Scholars:范功端)

Indexed by:

SCIE

Abstract:

Black-odorous waters are an increasingly common phenomenon characterized by excessive levels of nutrients, the formation of metal sufide precipitates, volatile sulfurous compounds, low dissolved oxygen and high chemical oxygen demand. Black-odorous waters frequently occur in lake and river systems where inputs have restricted circulation. The key remediation issue is the removal of nitrogen and phosphorus. Here, we present a novel aeration-adsorption system using fiber balls and we study treatment parameters and removal mechanism. Kinetics and changes of the solid phase were followed using Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. Results show complete removal of ammonia N, initially at 31 mg/L, and 92.8% removal of total nitrogen, initially at 29 mg/L, after a 24 h reaction time at pH 9.67. At pH 5.67 and 9.67, total phosphorus and phosphate could be significantly reduced by 90-92% at 3.2-5.2 mg/L after 24 h. Treatment met China's integrated wastewater discharge standards, demonstrating an effective and robust treatment capability. First-order and second-order kinetic models provided a good fit to the treatment data, indicating physical and chemical adsorption were involved in the treatment reactions. The reaction mechanism involved hydrogen substitution and binding to oxygen. These results present a cost effective and robust approach for the removal of N and P from black, odorous water, providing opportunity to abate environmental contamination.

Keyword:

Adsorption Aeration Black-odorous water Nitrogen Phosphorus Water pollution

Community:

  • [ 1 ] [Zhu, Guocheng]Hunan Univ Sci & Technol, Coll Civil Engn, Xiangtan 411201, Hunan, Peoples R China
  • [ 2 ] [Chen, Junming]Hunan Univ Sci & Technol, Coll Civil Engn, Xiangtan 411201, Hunan, Peoples R China
  • [ 3 ] [Zhang, Shanshan]Hunan Univ Sci & Technol, Coll Civil Engn, Xiangtan 411201, Hunan, Peoples R China
  • [ 4 ] [Luo, Huihao]Hunan Univ Sci & Technol, Coll Civil Engn, Xiangtan 411201, Hunan, Peoples R China
  • [ 5 ] [Zhao, Zilong]Harbin Inst Technol Shenzhen, Sch Civil & Environm Engn, Grad Sch, Shenzhen 518055, Peoples R China
  • [ 6 ] [Hursthouse, Andrew S.]Univ West Scotland, Sch Comp Engn & Phys Sci, Paisley PA1 2BE, Renfrew, Scotland
  • [ 7 ] [Wan, Peng]Shenzhen Water Planning & Design Inst Co Ltd, Guangdong Prov Engn & Technol Res Ctr Water Affai, Shenzhen 518001, Peoples R China
  • [ 8 ] [Fan, Gongduan]Fuzhou Univ, Coll Civil Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Hursthouse, Andrew S.]Univ West Scotland, Sch Comp Engn & Phys Sci, Paisley PA1 2BE, Renfrew, Scotland

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Source :

ENVIRONMENTAL CHEMISTRY LETTERS

ISSN: 1610-3653

Year: 2022

Issue: 4

Volume: 20

Page: 2243-2251

1 5 . 7

JCR@2022

1 5 . 0 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 21

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

Online/Total:107/10001337
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