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Abstract:
Purpose Kaolin has been commonly used to construct the hydraulic barrier of landfill cover. Reduction in desiccation-induced volume shrinkage of compacted kaolin is crucial to reduce the possibility of cracking during desiccation. Nano-biochar has been found to be a potential soil amendment. The present study aimed to investigate the effects of particle size of nano-biochar on the shrinkage behavior of kaolin amended with nano-biochar. Materials and methods The kaolin used in the present study had an average particle size of 14.5 mu m and was classified as high plasticity clay (CH). Two nano-biochars with the same composition but different average particle sizes were adopted, including NB-I of the average particle size of 20 nm and NB-II of 300 nm. Each type of nano-biochar was mixed with kaolin in different mass percentages, including 2%, 4%, 6%, and 10%.The shrinkage properties of pure kaolin and nano-biochar-amended kaolin were determined by wax method. Afterwards, the microstructure and pore-size distribution of the specimens were analyzed by scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP), respectively. Results and discussion The optimal content of NB-I was 4%, at which the shrinkage limit of kaolin increased by 66.7% (i.e., volume reduction decreased from about 30% to 10%), due to more micropores (pore diameter D < 1000 nm) but less macropores (D > 10,000 nm) after nano-biochar amendment as revealed by MIP test. Yet, the shrinkage limit of the kaolin decreased as NB-I content further increased, when NB-I content exceeded 4%. It was due to more macropores at higher NC-I content (> 4%) caused by the aggregation of the fine nano-particle. In contrast, the shrinkage limit of kaolin increased at a reduced rate as NC-II content increased, which was consistent with the more micropores observed in soil specimens. Conclusions Nano-biochar was a feasible soil amendment to enhance the shrinkage limit of kaolin and hence reduced the risk of desiccation-induced cracks. From an economic and practical point of view, 4% of NB-I was suggested to reduce volume shrinkage of kaolin and crack formation during desiccation.
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JOURNAL OF SOILS AND SEDIMENTS
ISSN: 1439-0108
Year: 2022
Issue: 5
Volume: 22
Page: 1511-1520
3 . 6
JCR@2022
2 . 8 0 0
JCR@2023
ESI Discipline: AGRICULTURAL SCIENCES;
ESI HC Threshold:48
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2