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Abstract:
Sunlight is an abundant and clean energy source, the harvesting of which could make a significant contribution to society's increasing energy demands. Metal halide perovskites (MHP) have recently received attention for solar fuel generation through photocatalysis and solar-driven electrocatalysis. However, MHP photocatalysis is limited by low solar energy conversion efficiency, poor stability, and impractical reaction conditions. Compared to photocatalysis, MHP solar-driven electrocatalysis not only exhibits higher solar conversion efficiency but also is more stable when operating under practical reaction conditions. In this Perspective, we outline three leading types of MHP solar-driven electrocatalysis device technologies now in the research spotlight, namely, (1) photovoltaic-electrochemical (PV-EC), (2) photovoltaic-photoelectrochemical (PV-PEC), and (3) photoelectrochemical (PEC) approaches for solar-to-fuel reactions, including water-splitting and the CO2 reduction reaction. In addition, we compare each technology to show their relative technical advantages and limitations and highlight promising research directions for the rapidly emerging scientific field of MHP-based solar-driven electrocatalysis.
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JOURNAL OF PHYSICAL CHEMISTRY LETTERS
ISSN: 1948-7185
Year: 2021
Issue: 1
Volume: 13
Page: 25-41
6 . 8 8 8
JCR@2021
4 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 17
SCOPUS Cited Count: 16
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: