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Abstract:
The urgent demand for high-performance energy storage components has been driving the exploration for superior battery-type electrode materials for hybrid supercapacitors, which is challenging but of considerable significance. In this paper, a one-step pyrolysis route was elaborated to prepare oxygen-enriched hierarchical porous carbon supported Co-Ni nanoparticles Co-Ni/OHPCs) by facile self-crosslinking assisted high internal phase emulsion (HIPE) templating. The oxygen-enriched porous carbon framework provides large specific surface area and structural stability, meanwhile Co doping can significantly reinforce the electrochemical performance of the Co-Ni/OHPCs battery-type electrodes. By optimizing the ratio of Ni2+ to Co2+ ions, the obtained Co-Ni/OHPC electrodes exhibited excellent electrochemical performance of 817.3 F g−1 at a scan rate of 5 mV s−1. Furthermore, coupling with an activated porous carbon anode, the assembled hybrid supercapacitor (HSC) possessed an appreciable energy density of 66.94 Wh kg−1 at 409.9 W kg−1 and a capacitance retention ratio of 73.89% after 5000 cycles, showing considerable application prospects. This structural design strategy provides new inspiration for the reasonable optimization of new electrode materials for promising hybrid supercapacitors. © 2022 Elsevier B.V.
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Journal of Alloys and Compounds
ISSN: 0925-8388
Year: 2022
Volume: 907
6 . 2
JCR@2022
5 . 8 0 0
JCR@2023
ESI HC Threshold:91
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 17
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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