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author:

Li, Chuntao (Li, Chuntao.) [1] | Cai, Zhenping (Cai, Zhenping.) [2] | Ma, Yongde (Ma, Yongde.) [3] | Cao, Yanning (Cao, Yanning.) [4] | Huang, Kuan (Huang, Kuan.) [5] | Jiang, Lilong (Jiang, Lilong.) [6]

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EI

Abstract:

Natural deep eutectic solvents (NADESs) are a subcategory of deep eutectic solvents (DESs) consisting solely of natural compounds. They can replace existing DESs that contain toxic compounds and are difficult to dispose of in many applications. However, the detailed physical properties data of NADESs are still very scarce in the literature. In this work, a series of NADESs with choline chloride (ChCl) as the shared hydrogen-bond acceptor (HBA), and five dicarboxylic acids (oxalic, malonic, maleic, malic and tartaric) as the varied hydrogen-bond donors (HBDs) were prepared. The densities and viscosities of prepared NADESs were determined from 293.2 to 353.2 K at 1.013 bar. The densities and viscosities data were fitted using empirical equations. An important application of DESs is gas separation, which requires knowing the solubilities of gases in DESs. Therefore, a NADES with relatively good fluidity was selected out as a representative to determine the solubilities of two typical acidic gases (SO2 and H2S) in it. The solubilities of SO2 and H2S were determined from 298.2 to 333.2 K and from 0 to 1 bar. The SO2 and H2S solubilities data were fitted using the Krichevsky − Kasarnovsky equation. © 2021 Elsevier Ltd

Keyword:

Chlorine compounds Density of gases Eutectics Gases Hydrogen bonds Oxalic acid Solubility Solvents Viscosity

Community:

  • [ 1 ] [Li, Chuntao]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 2 ] [Li, Chuntao]Beijing Sanju Environmental Protection & New Materials Co., Ltd, Beijing; 100080, China
  • [ 3 ] [Cai, Zhenping]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 4 ] [Ma, Yongde]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 5 ] [Cao, Yanning]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 6 ] [Huang, Kuan]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 7 ] [Jiang, Lilong]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350002, China

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Source :

Journal of Chemical Thermodynamics

ISSN: 0021-9614

Year: 2022

Volume: 167

2 . 6

JCR@2022

2 . 2 0 0

JCR@2023

ESI HC Threshold:74

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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