For　a　long　time,　carbon　has　been　an　ideal　material　for　various　electrochemical　energy　storage　devices　and　a　key　component　in　electrochemical　energy　storage　systems　due　to　its　advantages　of　rich　surface　states,　easy　tenability,　and　good　chemical　stability.　Stable　and　high-performance　carbon　materials　can　support　future　applications　of　high　specific　energy　electrodes.　Herein　and　for　the　first　time,　we　have　designed　nitrogen-doped　carbon　hollow　containers　using　oleylamine-coating　TiO2　mesocrystals　as　a　precursor　with　a　high　specific　surface　area　of　1231　m2　g−1.　When　applied　as　an　anode　for　lithium-ion　storage,　a　reversible　capacity　of　774.5　mA　h　g−1　is　obtained　at　a　rate　of　0.5　A　g−1　after　200　cycles.　Meanwhile,　at　an　even　higher　rate　of　2　A　g−1,　a　capacity　of　721.1　mA　h　g−1　is　still　achieved　after　500　cycles.　Moreover,　the　carbon　containers　remain　structurally　intact　after　a　series　of　cycles.　This　may　be　attributed　to　the　nitrogen　atoms　doped　on　the　carbon　surface　that　can　absorb　multiple　lithium　ions　and　enhance　the　structural　stability.　These　results　provide　technical　support　for　the　development　of　high　specific　energy　electrode　materials.　©　2022　Elsevier　Inc.