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Abstract:
Nanoporous metals have attracted much attention in energy storage due to their nanoporous structure, large specific surface area, three-dimensional (3D) conductive network, and excellent ductility. Especially as a current collector, nanoporous metals have unparalleled advantages. In this work, we develop a facile method to fabricate Si-Ni nanofoam composites for a high-loading Si anode in a lithium (Li)-ion battery. The Si particles in the composites take full advantage of Ni nanofoams to overcome the series of problems caused by the volume expansion of Si materials. By introducing a constant current-constant voltage mode, as a high-loading Si anode, the composite electrode exhibits high capacity and excellent cycling performance (1.39 mAh cm-2 after 100 cycles, with 69.5% capacity retention). In addition, the scanning electron microscopy (SEM) image after the cycles shows that the Ni nanofoams can play a role similar to the steel mesh in reinforced concrete, stabilize the composite electrode structure, and improve the Li storage performance. © 2022 American Chemical Society.
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ACS Applied Energy Materials
Year: 2022
Issue: 6
Volume: 5
Page: 7392-7399
6 . 4
JCR@2022
5 . 5 0 0
JCR@2023
ESI HC Threshold:91
JCR Journal Grade:1
CAS Journal Grade:3
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 4
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