The　biaryl　frameworks　are　momentous　organic　backbones　that　are　commonly　occurred　in　pharmaceutical,　functional　materials　and　natural　products.　By　virtue　of　the　distinctive　reactivity　through　state-of-the-art　process,　decarbonylative　couplings,　which　have　bypassed　the　restriction　to　specifically　substituted　(hetero)aryl　carboxylic　acids　of　decarboxylative　couplings,　gradually　become　unneglected　methods　in　the　conversion　of　carboxylic　acid　derivatives.　Herein,　a　rhodium-catalyzed　decarbonylative　Suzuki-Miyaura　cross-coupling　via　in-situ　generation　strategy　of　acyl　fluorides　from　carboxylic　acids　was　developed.　This　protocol　shows　eminent　functional　group　tolerance　with　arrays　of　combinations　between　carboxylic　acid　and　boronic　acid.　Furthermore,　the　reaction　offers　a　new　access　to　those　conventionally　unattainable　biaryl　motifs,　including　natural　product　and　modified　drugs.