ZnO　has　been　widely　employed　in　the　photodegradation　of　pollutants;　however,　it　exhibits　poor　photocatalytic　performance　under　visible　light　illumination.　Thus,　visible-light-driven　heterostructured　PVDF/ZnO/Ag2O　photocatalysts　were　fabricated　by　combining　the　electrospinning,　hydrothermal,　and　in　situ　deposition　tech-niques.　As　matrix　materials,　it　is　easy　to　recycle　and　reuse　electrospun　PVDF　nanofibers.　ZnO　nanorods　anchored　on　PVDF　nanofibers　with　a　high　specific　surface　area　provide　an　abundance　of　photocatalytically　active　sites.　As　a　photosensitizer,　silver　oxide　nanoparticles　enhance　the　visible-light　photocatalytic　efficiency.　Thus,　the　composited　PVDF/ZnO/Ag2O　photocatalysts　exhibit　excellent　photocatalytic　performance　under　both　UV　and　visible　light　irradiation　as　a　result　of　the　enhanced　electron-hole　separation/transfer　and　broadened　visible　light　absorption　range.　Under　visible　light　irradiation,　the　kinetic　constant　of　PVDF/ZnO/Ag2O　nanocomposites　is　24.4　and　6.73　times　greater　than　that　of　PVDF/Ag2O　and　PVDF/ZnO,　respectively.　Moreover,　the　PVDF/ZnO/　Ag2O　nanocomposites　exhibit　advantages　in　recycling　and　reusing　with　high　stability,　thus　considerably　widening　their　practical　applications　in　the　field　of　environmental　remediation.