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author:

Chen, Yumin (Chen, Yumin.) [1] | Yang, Huihui (Yang, Huihui.) [2] | Sun, Yuxuan (Sun, Yuxuan.) [3] | Li, Yafeng (Li, Yafeng.) [4] (Scholars:李亚峰) | Wei, Mingdeng (Wei, Mingdeng.) [5] (Scholars:魏明灯)

Indexed by:

EI Scopus SCIE

Abstract:

Transition metal oxides have attracted much attention in supercapacitors(SCs) research field due to their eco-friendly characteristics and high theoretical specific capacity. However, the slow reaction kinetics process and poor long-cycle performance hinder its potential application. To overcome these shortcomings, MnCo2O4 micro -flowers (MnCo2O4-MF) with hierarchical structure were prepared. The spinel MnCo2O4 has a variety of metal valence states, which can provide more electrochemical active sites compared to mono-metal oxides. Moreover, the unique hierarchical structure of MnCo2O4-MF shortens the transmission distance of ions and electrons, and reduce the volume expansion and structural collapse during the cycles. Benefiting from the crystal phase and structure advantages of MnCo2O4-MF, the reaction kinetics process was accelerated and it showed excellent long -cycle stability. In aqueous alkaline electrolyte, MnCo2O4-MF exhibits an ultra-high specific capacity of 1230 F g-1 at a current density of 1 A g-1. Even after 10,000 cycles at 10 A g-1, the capacity of 102.67% is still maintained. In addition, we constructed the sandwich structured flexible flexible hybrid solid supercapacitor (FHSC) based on MnCo2O4-MF // carbon nanoboxes. The FHSC devices not only expand the working voltage window of SCs, but also show flexibility and excellent electrochemical performance.

Keyword:

Flexible Hierarchical structure Hybrid solid supercapacitor MnCo2O4 micro-flowers

Community:

  • [ 1 ] [Chen, Yumin]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Yang, Huihui]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Sun, Yuxuan]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Li, Yafeng]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Wei, Mingdeng]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Li, Yafeng]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Wei, Mingdeng]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China

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Source :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

Year: 2022

Volume: 429

6 . 6

JCR@2022

5 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 14

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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