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author:

Mendoza, R. (Mendoza, R..) [1] | Oliva, J. (Oliva, J..) [2] | Padmasree, K.P. (Padmasree, K.P..) [3] | Mtz-Enriquez, A.I. (Mtz-Enriquez, A.I..) [4] | Hayat, A. (Hayat, A..) [5] | Rodriguez-Gonzalez, V. (Rodriguez-Gonzalez, V..) [6]

Indexed by:

Scopus

Abstract:

Electronic waste has become a serious worldwide problem due to the high consumption of electronic devices. To palliate this problem, we fabricated flexible and biodegradable supercapacitors (SCs) using electrodes made of avocado-peel + graphene (AVG electrode). The electrochemical efficiency of these SCs was enhanced by depositing LaMnO3 (LM) and LaSrMnO3 (LSM) perovskites on their electrodes. Those perovskites are formed by microparticles with irregular shape/morphology and have sizes of 0.8–4 μm. The electrochemical evaluation of the avocado based SCs revealed a maximum capacitance/energy-density of 1100.9 F g−1/97.8 Wh kg−1 and 703.7 F g−1/62.6 Wh kg−1 for the SCs containing the LaSrMnO3 and LaMnO3 perovskites (AVG/LM-SC and AVG/LSM-SC devices), respectively. If no perovskite is added on the SC electrodes, a lower capacitance/energy-density of 230.3 F g−1/18.1 Wh kg−1 is obtained (AVG-SC device). Thus, adding the Sr dopant in the LM perovskite deposited on the SCs electrodes improved the energy density and capacitance of the SCs by ~ 56% (with respect to the AVG/LM-SC device). The avocado based SCs were subjected to mechanical deformations (500 bending cycles) and the maximum loss of capacitance was 22.4, 14.3 and 11.5% for the AVG-SC, AVG/LM-SC and AVG/LSM-SC devices, respectively. In addition, the analysis by XPS, UV-VIS absorbance and Raman indicated the presence of the Mn2+/Mn3+/Mn4+ species and oxygen vacancies in the SCs and worked as redox sites for the storage of charge. In general, this investigation showed that efficient and biodegradable SCs can be fabricated using the avocado-peel, which is an abundant waste produced in the Mexican food industry. © 2022 Elsevier Ltd and Techna Group S.r.l.

Keyword:

Avocado peel Biodegradable Capacitance Energy density Graphene supercapacitor LaMnO3 perosvkite

Community:

  • [ 1 ] [Mendoza, R.]CONACYT-División de Materials Avanzados, Instituto Potosino de Investigación Científica y Tecnológica A. C, 78216 San Luis Potosí, SLP, Mexico
  • [ 2 ] [Oliva, J.]CONACYT-División de Materials Avanzados, Instituto Potosino de Investigación Científica y Tecnológica A. C, 78216 San Luis Potosí, SLP, Mexico
  • [ 3 ] [Padmasree, K.P.]Cinvestav Unidad Saltillo, Parque Industrial, Ramos Arizpe, Coahuila 25900, Mexico
  • [ 4 ] [Mtz-Enriquez, A.I.]Cinvestav Unidad Saltillo, Parque Industrial, Ramos Arizpe, Coahuila 25900, Mexico
  • [ 5 ] [Hayat, A.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Rodriguez-Gonzalez, V.]CONACYT-División de Materials Avanzados, Instituto Potosino de Investigación Científica y Tecnológica A. C, 78216 San Luis Potosí, SLP, Mexico

Reprint 's Address:

  • [Oliva, J.]CONACYT-División de Materials Avanzados, 78216 San Luis Potosí, SLP, Mexico

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Source :

Ceramics International

ISSN: 0272-8842

Year: 2022

Issue: 20

Volume: 48

Page: 30967-30977

5 . 2

JCR@2022

5 . 1 0 0

JCR@2023

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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