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author:

Li, Zhen (Li, Zhen.) [1] | Ren, Jing (Ren, Jing.) [2] | Bu, Jingting (Bu, Jingting.) [3] | Wang, Liang (Wang, Liang.) [4] | Shi, Wenyan (Shi, Wenyan.) [5] | Pan, Dengyu (Pan, Dengyu.) [6] | Wu, Minghong (Wu, Minghong.) [7] (Scholars:吴明红)

Indexed by:

SCIE

Abstract:

Graphene hydrogel (GH) has been widely explored as electrode material for supercapacitors due to its threedimensional porous network structure. However, poor conductivity and low capacitance activity have limited practical application. Herein, we design and fabricate a hierarchical all-carbon GH-based electrode material decorated with MOF-derived porous carbon (cZIF-8) and highly N-doped graphene quantum dots. In this N-GQD@cZIF-8/GHcomposite, GH constructs an interconnected porous structure which benefits rapid electron/ion transport, and cZIF-8 provides a large specific surface area and enhances electrical conductivity, while N-GQDs contribute pseudo-capacitance and improve the wettability. The supercapacitor based on N-GQD@cZIF-8/GH shows a high areal capacitance (617.1 mF cm(-2)) and areal energy density (85.7 mu Wh cm(-2)) at 1 mA cm(-2). It also has good rate capability (81.5% at 20 mA cm(-2)) and excellent cycling stability (93.1% after 10,000 cycles). Moreover, the assembled all-solid-state flexible supercapacitor can deliver a high energy density of 18.1 mWh cm(-3) at high power density of 4907.3 mW cm(-3). This rational-designed all-carbon electrode opens up opportunities in the fabrication of next-generation wearable electronic equipments.

Keyword:

Areal energy density cZIF-8 Graphene hydrogel N-doped graphene quantum dots Volumetric energy density

Community:

  • [ 1 ] [Li, Zhen]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 201800, Peoples R China
  • [ 2 ] [Ren, Jing]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 201800, Peoples R China
  • [ 3 ] [Bu, Jingting]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 201800, Peoples R China
  • [ 4 ] [Shi, Wenyan]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 201800, Peoples R China
  • [ 5 ] [Wang, Liang]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201800, Peoples R China
  • [ 6 ] [Pan, Dengyu]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201800, Peoples R China
  • [ 7 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201800, Peoples R China

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Source :

JOURNAL OF ELECTROANALYTICAL CHEMISTRY

ISSN: 1572-6657

Year: 2020

Volume: 876

4 . 4 6 4

JCR@2020

4 . 1 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 18

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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