The　hyperbranched　hydroxyl-rich　water-soluble　β-cyclodextrin　polymer　(β-CDp)　is　synthesized　by　the　reaction　between　β-cyclodextrin　and　1,　4-butanediol　diglycidyl　ether　with　a　facile　and　environmentally　friendly　method,　which　is　systematically　confirmed　using　Fourier　transform　infrared　spectroscopy　(FTIR),　X-ray　diffraction　(XRD)　and　thermogravimetric　(TG).　A　water-soluble　PAAS-β-CDp-PAA　binder　is　prepared　by　the　esterification　reaction　between　partially　neutralized　sodium　polyacrylate　(PAAS),　β-CDp,　and　polyacrylic　acid　(PAA).　Moreover,　the　optimized　PAAS6-β-CDp1-PAA3　binder,　with　a　three-dimensional　(3D)　cross-linked　network　structure　constructed　by　covalent　bonds,　hydrogen　bonds,　and　electrostatic　interactions,　displays　a　stronger　adhesion　between　the　active　material　and　the　current　collector,　effectively　promotes　the　diffusion　of　Li+,　and　maintains　the　structural　integrity　of　the　electrode　during　charge-discharge　cycling.　Thus　Si/PAAS6-β-CDp1-PAA3　electrode　exhibits　a　higher　initial　discharge　specific　capacity　of　3869　mAh　g−1　with　a　columbic　efficiency　of　89.79%　at　200　mA　g−1,　and　a　discharge　specific　capacity　of　2513　mAh　g−1　with　a　capacity　retention　rate　of　71.10%　is　achieved　after　100　cycles.　©　2022