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Abstract:
Two new extended polyoxometalate (POM) architectures based on lanthanide-incorporated polyoxoniobate (Ln-incorporated PONb) cages, namely, H4[CuII(en)2]4{K4(H2O)2[CuII(en)2]5[CuII5(trz)2(en)4 (OH)2] [Dy2CuII2(en)2(CO3)3(H2O)2(OH)3] [Dy(H2O)4] [DyNb23O68- (H2O)4]2}center dot 60H2O (1, en = ethylenediamine) and H20[CuII(en)2]4 {[CuII(en)2]4[Dy2(C2O4)(H2O)4]2[(Nb32(OH)4(H2O)3O89]2}center dot 54H2O (2), have been successfully synthesized and structurally characterized, demon-strating a feasible strategy to develop functional POM materials. In addition, the proton conductivity and magnetic behaviors of both 1 and 2 were studied.
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INORGANIC CHEMISTRY
ISSN: 0020-1669
Year: 2022
4 . 6
JCR@2022
4 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:74
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 16
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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