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author:

Wu, Xiaolin (Wu, Xiaolin.) [1] | Zhao, Junfeng (Zhao, Junfeng.) [2] | Liu, Wenyuan (Liu, Wenyuan.) [3] | Xie, Guiqing (Xie, Guiqing.) [4] | Ye, Zi (Ye, Zi.) [5] | Li, Zhiyuan (Li, Zhiyuan.) [6] | Sun, Hongjun (Sun, Hongjun.) [7]

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EI

Abstract:

The newly discovered Shuangjianzishan giant Ag-Pb-Zn deposit which located in the Southern segment of the Great Xing'an Range (SGXR), has controlled more than 18 000 t reserves of Ag, 1.9 Mt reserves of Zn, and 3.3 Mt reserves of Pb. Previous research has shown that Shuangjianzishan is a typical epithermal Ag-Pb-Zn deposit, however, mid- to high-temperature Cu-Sn (-W) mineralization are few studies. In this paper, a detailed mineralogical study reveals that a remarkable Cu-Sn (-W) mineralization is observed both in the upper tunnel and the deeper drill core samples. In the shallow ore-bodies, tin dominantly occurs as canfieldite in Pb-Zn-rich ores, minor as cassiterite-quartz veinlets. In the deep drill cores, tin occurs as cassiterite in the Cu-rich ores with the assemblage of quartz-arsenopyrite-chalcopyrite-stannite-(wolframite). Four primary paragenetic stages have been recognized. Stage I: cassiterite-quartz-arsenopyrite-chalcopyrite, including two sub-stage: cassiterite-arsenopyrite-pyrrhotite-quartz (stage I1) and sphalerite-chalcopyrite-galena-pyrite (stage I2); Stage II: galena-sphalerite-silver minerals; Stage III: Quartz-silver minerals, and stage IV: pyrite-carbonate. Electron probe micro-analysis (EPMA) show that the early mineralization (stage I) is characterized by Fe-rich sphalerite, Co-rich pyrite, Se-rich canfieldite, and Se-Bi-rich galena, while the later mineralization (stage II-IV) contains Fe-depleted sphalerite, As-rich pyrite, and Sb-bearing silver minerals. Laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis show that cassiterite has high contents of W, Fe, Sb, and Ti and depleted in Nb and Ta. Mineral associations and compositions implies a cassiterite-sulfide type tin mineralization in the Shuangjianzishan Ag-Pb-Zn deposit. A concealed granite porphyry intrusion was exposed in deep drill cores in the northwest part of the ore-field, with zircon U-Pb ages of (137.8 ± 1.1) Ma and (136.8 ± 1.0) Ma for fine- and coarse-grains granite, respectively. Bulk analysis shows that concealed granites are characterized by a highly fractionated, relatively reduced, and high K-calc-alkaline to alkaline, which belongs to A-type granites, and the remnant of Sn-bearing titanite suggests that it has the potential to provide the source of tin. Zircon U-Pb age (138–130 Ma) is well coupled with the previous data (ore-forming age, 136–129 Ma) of Shuangjianzishan, suggesting a close temporal and genetic relationship between tin mineralization and emplacement of the granite. This contribution implies that the Shuangjianzishan deposit may exist a middle- to high-temperature Cu-Sn (-W) mineralization center rather than a simple low-temperature hydrothermal system, and shows there is significant Sn-Cu mineralization potential in the peripheral and root zone of ore district. © 2022 The Author(s)

Keyword:

Antimony compounds Copper alloys Copper compounds Core drilling Deposits Drills Inductively coupled plasma mass spectrometry Infill drilling Laser ablation Lead alloys Mass spectrometers Mineralogy Pyrites Quartz Silver alloys Sulfide minerals Ternary alloys Tin alloys Tin compounds Zinc alloys Zinc sulfide

Community:

  • [ 1 ] [Wu, Xiaolin]Zijin School of Geology and Mining, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Wu, Xiaolin]School of Earth Sciences and Resources, China University of Geosciences, Beijing; 100083, China
  • [ 3 ] [Zhao, Junfeng]Zijin School of Geology and Mining, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Zhao, Junfeng]CAS Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou; 510640, China
  • [ 5 ] [Zhao, Junfeng]College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing; 100049, China
  • [ 6 ] [Liu, Wenyuan]Zijin School of Geology and Mining, Fuzhou University, Fuzhou; 350108, China
  • [ 7 ] [Xie, Guiqing]Zijin School of Geology and Mining, Fuzhou University, Fuzhou; 350108, China
  • [ 8 ] [Xie, Guiqing]School of Earth Sciences and Resources, China University of Geosciences, Beijing; 100083, China
  • [ 9 ] [Ye, Zi]Zijin School of Geology and Mining, Fuzhou University, Fuzhou; 350108, China
  • [ 10 ] [Li, Zhiyuan]Chifeng Yubang Mining Company, Chifeng; 024000, China
  • [ 11 ] [Sun, Hongjun]Chifeng Yubang Mining Company, Chifeng; 024000, China

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Source :

Ore Geology Reviews

ISSN: 0169-1368

Year: 2023

Volume: 152

3 . 2

JCR@2023

3 . 2 0 0

JCR@2023

ESI HC Threshold:26

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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