The　utilization　of　solar　light　to　trigger　organic　syntheses　for　the　production　of　value-added　chemicals　has　attracted　increasing　recent　research　attention.　The　integration　of　plasmonic　AuNPs　(NPs　=　nanoparticles)　with　MOFs　would　provide　a　new　way　for　the　development　of　highly　efficient　photocatalytic　systems.　In　this　manuscript,　a　bottle-around-ship　strategy　was　adopted　for　the　successful　synthesis　of　a　core-shell　structured　Au-pvp@MIL-100(Fe)　(PVP　=　polyvinylpyrrolidone)　nanocomposite　in　room　temperature.　The　as-obtained　core-shell　structured　Au-pvp@MIL-100(Fe)　show　improved　photocatalytic　performance　for　benzyl　alcohol　oxidation　under　visible　light,　because　of　the　migration　of　the　surface　plasmon　resonance　(SPR)　excited　hot　electrons　from　plasmonic　Au　NPs　to　MIL-100(Fe),　resulting　in　the　production　of　more　active　O-2(center　dot-)　radicals.　The　removal　of　the　capping　agent　PVP　from　Au-pvp@MIL-100(Fe)　significantly　enhanced　the　photocatalytic　performance,　because　of　an　improved　charge　transfer　from　plasmonic　Au　NPs　to　MIL-100(Fe).　This　study　demonstrates　an　efficient　strategy　of　fabricating　superior　photocatalytic　systems　by　a　rational　coupling　of　plasmonic　Au　NPs　and　photocatalytic　active　MOFs　into　a　core-shell　structured　nanocomposite.