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Abstract:
With the advantages of low cost, high safety, and environmental friendliness, quasi-solid-state zinc-ion microbatteries (ZIMBs) have received widespread attention in the field of flexible wearable devices and on-chip integratable energy storage. However, hysteresis Zn-ion transport kinetics and inhomogeneous growth of the zinc anode result in the poor capacity reversibility and cycling stability. Herein, a quasi-solid-state planar zinc-ion cell was developed by employing a vertical graphene (VG) film as an effective conductive modification layer for both the cathode and anode. The VG distinctly induces uniform Zn deposition/stripping, accelerates the charge transport, and enhances the adhesion between the active materials and current collectors. As a result, planar Zn@VG//MnO2@VG exhibits a high areal capacity of 159 mu Ah cm-2, a remarkably high areal energy/power density of 201.5 mu Wh cm-2/67.16 mu W cm-2, and a high capacity retention of 95.6% at a bending angle of 180 degrees. The proposed facile strategy for electrode modification provides a new insight into the design of high-performance flexible and planar ZIMBs.
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ACS APPLIED MATERIALS & INTERFACES
ISSN: 1944-8244
Year: 2023
8 . 5
JCR@2023
8 . 5 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:49
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 12
SCOPUS Cited Count: 14
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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