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author:

Liu, X. (Liu, X..) [1] | Wang, F. (Wang, F..) [2] | Xia, C. (Xia, C..) [3] | You, Q. (You, Q..) [4] | Chen, X. (Chen, X..) [5] | Li, Y. (Li, Y..) [6] (Scholars:李奕) | Lin, W. (Lin, W..) [7] | Guo, L. (Guo, L..) [8] | Fu, F. (Fu, F..) [9]

Indexed by:

Scopus

Abstract:

Herein, a new strategy for laccase-like nanozyme is proposed by utilizing copper nanoparticles (Cu NPs) as the active center, carbon nitride as the skeleton and triazole groups as the cofactor. Cu NPs incorporated nitrogen-rich carbon nitride (Cu-g-C3N5) nanocomposites are found to possess excellent laccase-like activity, which can catalyze the oxidation of bisphenol A (BPA) to produce a color change in the presence of 4-aminoantipyrine. The catalytic efficiency of Cu-g-C3N5 nanocomposites is 4-fold higher than their analogue (Cu-g-C3N4 nanocomposites) without triazole groups. Cu-g-C3N5 nanocomposites also display robust catalytic activity with high temperature stability, resistance to acid and alkalinity, and long term stability. Density functional theory calculations indicate that triazole groups are beneficial to improve the stability of Cu NPs via additional Cu-N bonds and facilitate the activation of the adsorbed O2 molecules. There is a linear relationship between the absorbance and BPA concentration over the range of 0.25–25 mg L−1 with the limit of detection of 0.09 mg L−1. Finally, Cu-g-C3N5 nanocomposites are successfully applied for colorimetric detection of BPA released from polycarbonate microplastics. To the best of our knowledge, this is the first example to utilize laccase-like nanozyme for colorimetric detection of BPA. © 2023 Elsevier B.V.

Keyword:

Bisphenol A Cofactor Laccase Microplastics Nanozyme

Community:

  • [ 1 ] [Liu, X.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Liu, X.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Wang, F.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Xia, C.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Xia, C.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 6 ] [You, Q.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 7 ] [You, Q.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 8 ] [Chen, X.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 9 ] [Li, Y.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 10 ] [Li, Y.]Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, Xiamen, 361005, China
  • [ 11 ] [Lin, W.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 12 ] [Lin, W.]Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, Xiamen, 361005, China
  • [ 13 ] [Guo, L.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 14 ] [Guo, L.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 15 ] [Fu, F.]Ministry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 16 ] [Fu, F.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • 李奕

    [Li, Y.]College of Chemistry, China

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Source :

Microchemical Journal

ISSN: 0026-265X

Year: 2023

Volume: 190

4 . 9

JCR@2023

4 . 9 0 0

JCR@2023

ESI HC Threshold:39

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 13

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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