Two new inorganic-organic hybrid polyoxotantalates with proton conduction property - Details

author：

Wang, Y.-L. (Wang, Y.-L..) ^[1] | Wu, Y.-L. (Wu, Y.-L..) ^[2] | Zeng, Q.-X. (Zeng, Q.-X..) ^[3] | Li, X.-X. (Li, X.-X..) ^[4] | Zheng, S.-T. (Zheng, S.-T..) ^[5]

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Abstract：

Two　new　inorganic-organic　hybrid　polyoxotantalates　(POTas),　H2[Co(en)3]3Ta6O19　(1)　and　Na2(H2O)6H2[Co(en)3]2Ta6O19　(2)　(en　=　ethylenediamine)　have　been　hydrothermally　synthesized　by　using　the　phosphate　buffer　solution　(Na3PO4/Na2HPO4,　pH　=　12.36)　as　reaction　medium.　Notably,　both　compounds　are　built　from　anionic　[Ta6O19]8−　clusters　and　[Co(en)3]2+　complexes,　showing　good　stability.　Moreover,　it　is　demonstrated　that　both　compounds　exhibit　moderate　proton　conduction　properties.　©　2023　Elsevier　Inc.

Keyword：

Polyoxometalate Polyoxotantalates Proton conduction

Community：

[ 1 ] [Wang, Y.-L.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 2 ] [Wu, Y.-L.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 3 ] [Zeng, Q.-X.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 4 ] [Li, X.-X.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 5 ] [Li, X.-X.]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071, China
[ 6 ] [Zheng, S.-T.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China

Reprint 's Address：

[Li, X.-X.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials, Fujian, China;;[Zeng, Q.-X.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials, Fujian, China

Email：

lxx@fzu.edu.cn |
T04007@fzu.edu.cn

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Source ：

Journal of Solid State Chemistry

ISSN： 0022-4596

Year： 2023

Volume： 322

3 . 2

JCR@2023

3 . 2 0 0

JCR@2023

ESI HC Threshold：39

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 2

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