Two new inorganic-organic hybrid polyoxotantalates with proton conduction property - Details

author：

Wang, Yi-Lun (Wang, Yi-Lun.) ^[1] | Wu, Yan-Lan (Wu, Yan-Lan.) ^[2] | Zeng, Qing-Xin (Zeng, Qing-Xin.) ^[3] (Scholars：曾庆新) | Li, Xin-Xiong (Li, Xin-Xiong.) ^[4] (Scholars：李新雄) | Zheng, Shou-Tian (Zheng, Shou-Tian.) ^[5] (Scholars：郑寿添)

Indexed by：

EI Scopus SCIE

Abstract：

Two　new　inorganic-organic　hybrid　polyoxotantalates　(POTas),　H2[Co(en)3]3Ta6O19　(1)　and　Na2(H2O)6H2[-Co(en)3]2Ta6O19　(2)　(en　=　ethylenediamine)　have　been　hydrothermally　synthesized　by　using　the　phosphate　buffer　solution　(Na3PO4/Na2HPO4,　pH　=　12.36)　as　reaction　medium.　Notably,　both　compounds　are　built　from　anionic　[Ta6O19]8-clusters　and　[Co(en)3]2+　complexes,　showing　good　stability.　Moreover,　it　is　demonstrated　that　both　compounds　exhibit　moderate　proton　conduction　properties.

Keyword：

Polyoxometalate Polyoxotantalates Proton conduction

Community：

[ 1 ] [Wang, Yi-Lun]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350108, Fujian, Peoples R China
[ 2 ] [Wu, Yan-Lan]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350108, Fujian, Peoples R China
[ 3 ] [Zeng, Qing-Xin]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350108, Fujian, Peoples R China
[ 4 ] [Li, Xin-Xiong]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350108, Fujian, Peoples R China
[ 5 ] [Zheng, Shou-Tian]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350108, Fujian, Peoples R China
[ 6 ] [Li, Xin-Xiong]Nankai Univ, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China

Reprint 's Address：

[Zeng, Qing-Xin]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350108, Fujian, Peoples R China;;[Li, Xin-Xiong]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350108, Fujian, Peoples R China;;

Email：

T04007@fzu.edu.cn |
lxx@fzu.edu.cn

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