The　efficient　and　economic　heteroatom-implanting　method　for　MWW-type　zeolite　has　been　the　focus　of　attention　and　needs　further　exploration.　Ti　incorporated　MWW　zeolite　was　synthesized　by　sequential　treatment　of　boron-containing　zeolite　precursor.　The　catalysts　were　applied　to　the　epoxidation　of　1-hexene.　The　implanting　titanium　process　was　conducted　under　a　mild　condition　with　Ti(SO4)2/NH4HF2/HNO3　solution,　and　the　product　Ti-MWW　precursors　have　framework　titanium　alone,　the　novel　method　is　named　as　refluxing　and　implanting　titanium　method　which　integrates　acid　treatment　and　titanium　incorporation　into　one　step　and　reduces　the　consumption　of　time　of　this　process　into　1 h.　A　density　functional　theory　was　conducted　to　explain　the　formation　mechanism　of　interlayer-expanded　structure　of　Ti-MWW　zeolite.　Subsequently,　Ti-MWW　precursors　were　treated　in　modified　reagent　solution　to　obtain　larger　pore　structure,　which　increase　the　conversion　of　1-hexene　from　20.45　to　62.96%.　The　catalytic　performance　of　Ti-MWW　zeolite　in　this　work　are　superior　to　Ti-MWW　zeolite　synthesized　by　traditional　dry-gel　conversion　method　the　conversion　of　1-hexene　of　which　was　4.2%.　This　novel　method　is　a　promising　approach　for　the　synthesis　of　high　catalytic　performance　heteroatomic　zeolite.　Graphical　abstract:　[Figure　not　available:　see　fulltext.].　©　2022,　The　Author(s),　under　exclusive　licence　to　Springer　Science+Business　Media,　LLC,　part　of　Springer　Nature.