Login | Cas Login
English| 简体中文| 繁体中文

  • Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

Advanced Search

author：

Qiu, Z. (Qiu, Z..) [1] | Shen, S. (Shen, S..) [2] | Liu, P. (Liu, P..) [3] | Li, C. (Li, C..) [4] | Zhong, Y. (Zhong, Y..) [5] | Su, H. (Su, H..) [6] | Xu, X. (Xu, X..) [7] | Zhang, Y. (Zhang, Y..) [8] | Cao, F. (Cao, F..) [9] | Noori, A. (Noori, A..) [10] | Mousavi, M.F. (Mousavi, M.F..) [11] | Chen, M. (Chen, M..) [12] | He, X. (He, X..) [13] | Xia, X. (Xia, X..) [14] | Xia, Y. (Xia, Y..) [15] | Zhang, W. (Zhang, W..) [16] | Tu, J. (Tu, J..) [17]

Indexed by：

Scopus

Abstract：

Construction　of　high　efficiency　and　stable　Li　metal　anodes　is　extremely　vital　to　the　breakthrough　of　Li　metal　batteries.　In　this　study,　for　the　first　time,　groundbreaking　in　situ　plasma　interphase　engineering　is　reported　to　construct　high-quality　lithium　halides-dominated　solid　electrolyte　interphase　layer　on　Li　metal　to　stabilize　&　protect　the　anode.　Typically,　SF6　plasma-induced　sulfured　and　fluorinated　interphase　(SFI)　is　composed　of　LiF　and　Li2S,　interwoven　with　each　other　to　form　a　consecutive　solid　electrolyte　interphase.　Simultaneously,　brand-new　vertical　Co　fibers　(diameter:　≈5 µm)　scaffold　is　designed　via　a　facile　magnetic-field-assisted　hydrothermal　method　to　collaborate　with　plasma-enhanced　Li　metal　anodes　(SFI@Li/Co).　The　Co　fibers　scaffold　accommodates　active　Li　with　mechanical　integrity　and　decreases　local　current　density　with　good　lithiophilicity　and　low　geometric　tortuosity,　supported　by　DFT　calculations　and　COMSOL　Multiphysics　simulation.　Consequently,　the　assembled　symmetric　cells　with　SFI@Li/Co　anodes　exhibit　superior　stability　over　525 h　with　a　small　voltage　hysteresis　(125 mV　at　5 mA cm−2)　and　improved　Coulombic　efficiency　(99.7%),　much　better　than　the　counterparts.　Enhanced　electrochemical　performance　is　also　demonstrated　in　full　cells　with　commercial　cathodes　and　SFI@Li/Co　anode.　The　research　offers　a　new　route　to　develop　advanced　alkali　metal　anodes　for　energy　storage.　©　2023　Wiley-VCH　GmbH.

Keyword：

cobalt fibers lithium batteries lithium metal anode plasma solid electrolyte interphases

Community：

  • [ 1 ] [Qiu, Z.]State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 2 ] [Qiu, Z.]College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014, China
  • [ 3 ] [Shen, S.]State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 4 ] [Liu, P.]State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 5 ] [Li, C.]Institute of Fundamental and Frontier Science, University of Electronic Science and Technology of China, Chengdu, 611371, China
  • [ 6 ] [Zhong, Y.]State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 7 ] [Su, H.]State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 8 ] [Xu, X.]State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 9 ] [Zhang, Y.]Institute of Fundamental and Frontier Science, University of Electronic Science and Technology of China, Chengdu, 611371, China
  • [ 10 ] [Cao, F.]Department of Engineering Technology, Huzhou College, Huzhou, 313000, China
  • [ 11 ] [Noori, A.]Department of Chemistry, Faculty of Basic Sciences, Tarbiat Modares University, Tehran, 14117-13116, Iran
  • [ 12 ] [Mousavi, M.F.]Department of Chemistry, Faculty of Basic Sciences, Tarbiat Modares University, Tehran, 14117-13116, Iran
  • [ 13 ] [Chen, M.]Key Laboratory of Engineering Dielectric and Applications (Ministry of Education), School of Electrical and Electronic Engineering, Harbin University of Science and Technology, Harbin, 150080, China
  • [ 14 ] [He, X.]College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014, China
  • [ 15 ] [Xia, X.]State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 16 ] [Xia, X.]College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014, China
  • [ 17 ] [Xia, X.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 18 ] [Xia, Y.]College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014, China
  • [ 19 ] [Zhang, W.]College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014, China
  • [ 20 ] [Tu, J.]State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, China

Reprint 's Address：

  • [Zhong, Y.]State Key Laboratory of Silicon Materials, China;;[Xia, X.]State Key Laboratory of Silicon Materials, China;;[Zhang, Y.]Institute of Fundamental and Frontier Science, China

Email：


yu_zhong@zju.edu.cn |
helloxxh@zju.edu.cn |
yqzhang@uestc.edu.cn
Show more details

Related Keywords：

Related Article：

Source ：

Advanced Functional Materials

ISSN： 1616-301X

Year： 2023

Issue： 16

Volume： 33

1 8 . 5

JCR@2023

1 8 . 5 0 0

JCR@2023

ESI HC Threshold：49

JCR Journal Grade：1

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 6

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS
Online/Total：254/10044559
Address：FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code：350116) Contact Us：0591-22865326
Copyright：FZU Library Technical Support：Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1