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author:

Li, Borong (Li, Borong.) [1] | Chao, Yu (Chao, Yu.) [2] | Li, Mengchao (Li, Mengchao.) [3] | Xiao, Yuanbin (Xiao, Yuanbin.) [4] | Li, Rui (Li, Rui.) [5] | Yang, Kang (Yang, Kang.) [6] | Cui, Xiancai (Cui, Xiancai.) [7] | Xu, Gui (Xu, Gui.) [8] | Li, Lingyun (Li, Lingyun.) [9] (Scholars:李凌云) | Yang, Chengkai (Yang, Chengkai.) [10] | Yu, Yan (Yu, Yan.) [11] | Wilkinson, David P. (Wilkinson, David P..) [12] | Zhang, Jiujun (Zhang, Jiujun.) [13] (Scholars:张久俊)

Indexed by:

EI Scopus SCIE CSCD

Abstract:

Lithium-metal batteries with high energy/power densities have significant applications in electronics, electric vehicles, and stationary power plants. However, the unstable lithium-metal-anode/electrolyte interface has induced insufficient cycle life and safety issues. To improve the cycle life and safety, understanding the formation of the solid electrolyte interphase (SEI) and growth of lithium dendrites near the anode/electrolyte interface, regulating the electrodeposition/electrostripping processes of Li+, and developing multiple approaches for protecting the lithium-metal surface and SEI layer are crucial and necessary. This paper comprehensively reviews the research progress in SEI and lithium dendrite growth in terms of their classical electrochemical lithium plating/stripping processes, interface interaction/nucleation processes, anode geometric evolution, fundamental electrolyte reduction mechanisms, and effects on battery performance. Some important aspects, such as charge transfer, the local current distribution, solvation, desolvation, ion diffusion through the interface, inhibition of dendrites by the SEI, additives, models for dendrite formation, heterogeneous nucleation, asymmetric processes during stripping/plating, the host matrix, and in situ nucleation characterization, are also analyzed based on experimental observations and theoretical calculations. Several technical challenges in improving SEI properties and reducing lithium dendrite growth are analyzed. Furthermore, possible future research directions for overcoming the challenges are also proposed to facilitate further research and development toward practical applications.

Keyword:

Additives Asymmetric processes Classical electrochemical processes Dendrite formation Desolvation Heterogeneous nucleation In situ characterization of nucleation Lithium batteries Lithium-metal anode Solid electrolyte interphase (SEI) Solvation structure

Community:

  • [ 1 ] [Li, Borong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Chao, Yu]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Li, Mengchao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Xiao, Yuanbin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Li, Rui]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Yang, Kang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 7 ] [Cui, Xiancai]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Xu, Gui]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Li, Lingyun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Yang, Chengkai]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 12 ] [Zhang, Jiujun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 13 ] [Li, Borong]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 14 ] [Chao, Yu]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 15 ] [Li, Mengchao]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 16 ] [Xiao, Yuanbin]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 17 ] [Li, Rui]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 18 ] [Yang, Kang]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 19 ] [Cui, Xiancai]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 20 ] [Xu, Gui]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 21 ] [Li, Lingyun]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 22 ] [Yang, Chengkai]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 23 ] [Yu, Yan]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China
  • [ 24 ] [Wilkinson, David P.]Univ British Columbia, Dept Chem & Biochem Engn, Vancouver, BC V6T 1W5, Canada
  • [ 25 ] [Zhang, Jiujun]Univ British Columbia, Dept Chem & Biochem Engn, Vancouver, BC V6T 1W5, Canada
  • [ 26 ] [Zhang, Jiujun]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China

Reprint 's Address:

  • [Yang, Chengkai]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Zhang, Jiujun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Yang, Chengkai]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China;;[Yu, Yan]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350108, Fujian, Peoples R China;;[Zhang, Jiujun]Univ British Columbia, Dept Chem & Biochem Engn, Vancouver, BC V6T 1W5, Canada;;[Zhang, Jiujun]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China;;

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Source :

ELECTROCHEMICAL ENERGY REVIEWS

ISSN: 2520-8489

Year: 2023

Issue: 1

Volume: 6

2 8 . 5

JCR@2023

2 8 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:39

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 68

SCOPUS Cited Count: 69

ESI Highly Cited Papers on the List: 6 Unfold All

  • 2025-1
  • 2024-11
  • 2024-9
  • 2024-7
  • 2024-5
  • 2024-3

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

Online/Total:221/10000547
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