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author:

Wu, X. (Wu, X..) [1] | Zhao, J. (Zhao, J..) [2] | Liu, W. (Liu, W..) [3] | Xie, G. (Xie, G..) [4] | Ye, Z. (Ye, Z..) [5] | Li, Z. (Li, Z..) [6] | Sun, H. (Sun, H..) [7]

Indexed by:

Scopus

Abstract:

The newly discovered Shuangjianzishan giant Ag-Pb-Zn deposit which located in the Southern segment of the Great Xing'an Range (SGXR), has controlled more than 18 000 t reserves of Ag, 1.9 Mt reserves of Zn, and 3.3 Mt reserves of Pb. Previous research has shown that Shuangjianzishan is a typical epithermal Ag-Pb-Zn deposit, however, mid- to high-temperature Cu-Sn (-W) mineralization are few studies. In this paper, a detailed mineralogical study reveals that a remarkable Cu-Sn (-W) mineralization is observed both in the upper tunnel and the deeper drill core samples. In the shallow ore-bodies, tin dominantly occurs as canfieldite in Pb-Zn-rich ores, minor as cassiterite-quartz veinlets. In the deep drill cores, tin occurs as cassiterite in the Cu-rich ores with the assemblage of quartz-arsenopyrite-chalcopyrite-stannite-(wolframite). Four primary paragenetic stages have been recognized. Stage I: cassiterite-quartz-arsenopyrite-chalcopyrite, including two sub-stage: cassiterite-arsenopyrite-pyrrhotite-quartz (stage I1) and sphalerite-chalcopyrite-galena-pyrite (stage I2); Stage II: galena-sphalerite-silver minerals; Stage III: Quartz-silver minerals, and stage IV: pyrite-carbonate. Electron probe micro-analysis (EPMA) show that the early mineralization (stage I) is characterized by Fe-rich sphalerite, Co-rich pyrite, Se-rich canfieldite, and Se-Bi-rich galena, while the later mineralization (stage II-IV) contains Fe-depleted sphalerite, As-rich pyrite, and Sb-bearing silver minerals. Laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis show that cassiterite has high contents of W, Fe, Sb, and Ti and depleted in Nb and Ta. Mineral associations and compositions implies a cassiterite-sulfide type tin mineralization in the Shuangjianzishan Ag-Pb-Zn deposit. A concealed granite porphyry intrusion was exposed in deep drill cores in the northwest part of the ore-field, with zircon U-Pb ages of (137.8 ± 1.1) Ma and (136.8 ± 1.0) Ma for fine- and coarse-grains granite, respectively. Bulk analysis shows that concealed granites are characterized by a highly fractionated, relatively reduced, and high K-calc-alkaline to alkaline, which belongs to A-type granites, and the remnant of Sn-bearing titanite suggests that it has the potential to provide the source of tin. Zircon U-Pb age (138–130 Ma) is well coupled with the previous data (ore-forming age, 136–129 Ma) of Shuangjianzishan, suggesting a close temporal and genetic relationship between tin mineralization and emplacement of the granite. This contribution implies that the Shuangjianzishan deposit may exist a middle- to high-temperature Cu-Sn (-W) mineralization center rather than a simple low-temperature hydrothermal system, and shows there is significant Sn-Cu mineralization potential in the peripheral and root zone of ore district. © 2022 The Author(s)

Keyword:

Cassiterite Mineralogy Shuangjianzishan Ag-Pb-Zn deposit Tin mineralization

Community:

  • [ 1 ] [Wu, X.]Zijin School of Geology and Mining, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Wu, X.]School of Earth Sciences and Resources, China University of Geosciences, Beijing, 100083, China
  • [ 3 ] [Zhao, J.]Zijin School of Geology and Mining, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Zhao, J.]CAS Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, China
  • [ 5 ] [Zhao, J.]College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
  • [ 6 ] [Liu, W.]Zijin School of Geology and Mining, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Xie, G.]Zijin School of Geology and Mining, Fuzhou University, Fuzhou, 350108, China
  • [ 8 ] [Xie, G.]School of Earth Sciences and Resources, China University of Geosciences, Beijing, 100083, China
  • [ 9 ] [Ye, Z.]Zijin School of Geology and Mining, Fuzhou University, Fuzhou, 350108, China
  • [ 10 ] [Li, Z.]Chifeng Yubang Mining Company, Chifeng, 024000, China
  • [ 11 ] [Sun, H.]Chifeng Yubang Mining Company, Chifeng, 024000, China

Reprint 's Address:

  • [Liu, W.]Zijin School of Geology and Mining, China

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Source :

Ore Geology Reviews

ISSN: 0169-1368

Year: 2023

Volume: 152

3 . 2

JCR@2023

3 . 2 0 0

JCR@2023

ESI HC Threshold:26

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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