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author：

Song, Y. (Song, Y..) [1] | Fu, J.-H. (Fu, J.-H..) [2] | Tan, B.-C. (Tan, B.-C..) [3] | Wang, Q. (Wang, Q..) [4] | Jiang, L.-L. (Jiang, L.-L..) [5] | Wu, X.-T. (Wu, X.-T..) [6] | Sheng, T.-L. (Sheng, T.-L..) [7]

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Scopus

Abstract：

Two　pairs　of　cyanidometal-bridged　trinuclear　complexes　trans-[Cp*(modppe)Ru(μ-NC)Ru(L)4(μ-CN)Ru(modppe)Cp*][PF6]n　(n　=　2,　3;　L　=　pyridine　(py),　1[PF6]n;　4-methoxypyridine　(mopy),　2[PF6]n;　Cp*　=　1,2,3,4,5-pentamethylcyclopentadiene)　in　two　distinct　states　have　been　synthesized　and　fully　characterized.　The　investigated　results　suggest　that　1[PF6]3　and　2[PF6]3　are　Class　II　mixed　valence　complexes.　The　IR　spectroscopy　and　UV–vis-NIR　spectroscopy　analyses　showed　that　with　the　increase　of　the　electron-donating　ability　of　the　auxiliary　ligand　of　the　cyanidometal　bridge,　the　degree　of　delocalization　increases　and　the　energy　of　the　metal-to-metal　charge　transfer　(MMCT)　of　the　mixed　valence　complexes　decreases,　supported　by　TDDFT　calculations.　©　2023　Elsevier　Ltd

Keyword：

Class II Cyanidometal-bridged Metal to metal charge transfer (MMCT) Mixed-valence Ru

Community：

  • [ 1 ] [Song Y.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Song Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 3 ] [Fu J.-H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 4 ] [Tan B.-C.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 5 ] [Wang Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 6 ] [Jiang L.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 7 ] [Wu X.-T.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 8 ] [Sheng T.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

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Source ：

Polyhedron

ISSN： 0277-5387

Year： 2023

Volume： 240

2 . 4

JCR@2023

2 . 4 0 0

JCR@2023

ESI HC Threshold：39

JCR Journal Grade：2

CAS Journal Grade：3

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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