alpha-Boryl　carbonyl　species　and　alpha-boryl　aminocompoundsare　valuable　and　important　frameworks　in　organic　synthesis.　However,the　strategies　that　could　merge　the　two　scaffolds　into　one　compound,named　1,1-carbonyl　amino　alkyl　boron,　are　elusive　and　underdeveloped.Herein,　we　present　an　efficient　method　that　could　address　this　gapand　produce　1,1-carbonyl　amino　alkyl　borons　from　readily　accessibleindoles　via　oxidation　by　m-CPBA　or　oxone.　This　reactionfeatures　operational　simplicity,　divergent　synthesis,　broad　substratescope,　and　valuable　products.