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author:

Chen, Nange (Chen, Nange.) [1] | Zhang, Guanjun (Zhang, Guanjun.) [2] | Chen, Huixin (Chen, Huixin.) [3] | Yue, Hongjun (Yue, Hongjun.) [4]

Indexed by:

Scopus SCIE

Abstract:

Lithium/carbon fluoride (Li/CFx) batteries have been widely researched due to their high theoretical specific energy. To create a high-performance electrode, the fluorinated hard carbon (FHC) is prepared by direct gas-phase fluorination. It has a high F/C ratio of 0.95 based on the gravimetric method. Selecting hard carbon (HC) with a high surface area as the carbon source allows for FHC to achieve suitable interlayer spacing and specific surface area, as well as abundant pore structures to facilitate rapid lithium ion transportation. Additionally, a composite of graphene and carbon nanotubes (CNTs) is coated on the surface of FHC, enhancing electron transport speed. The resulting FHC&C exhibits a very high energy density of 1256 Wh kg(-1) and an excellent power density of 72,929 W kg(-1) at a high rate of 40 C. Moreover, compared to commercial CFx, FHC&C exhibits higher energy and power densities, thus presenting a promising practical application prospect.

Keyword:

carbon fluoride composite hard carbon primary lithium battery

Community:

  • [ 1 ] [Chen, Nange]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Chen, Nange]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 3 ] [Chen, Huixin]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 4 ] [Yue, Hongjun]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Peoples R China
  • [ 5 ] [Chen, Nange]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 6 ] [Chen, Huixin]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 7 ] [Yue, Hongjun]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China
  • [ 8 ] [Zhang, Guanjun]Tianjin Lantian Special Power Supply Sci & Technol, Tianjin 300393, Peoples R China

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Source :

COATINGS

ISSN: 2079-6412

Year: 2023

Issue: 5

Volume: 13

2 . 9

JCR@2023

2 . 9 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:49

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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