Photoactive　Cu(I)　complexes　are　promising　luminescent　materials　owing　to　their　abundant　reserves　and　marvelous　biocompatibility.　In　this　work,　we　report　the　synthesis　and　characterization　of　two　binuclear　sulfur-bridged　Cu(I)　complexes　(POP)(2)Cu-2(mu-HS/Cl)(2)center　dot　0.92MeOH　1　(POP=(oxybis(2,1-phenylene))bis(diphenylphosphine))　and　(POP)(2)Cu-2(mu-HS)(2)　2,　which　were　prepared　by　one-pot　facile　solvothermal　method　with　copper-4-tert-butylbenzenethiol　((CuSC6H4Bu)-Bu-t)　and　POP　as　precursors.　Complex　1　exhibits　sky-blue　emission　while　complex　2　displays　blue.　Complex　1　was　systemically　investigated　by　PXRD,　UV-vis　spectrum,　IR,　TGA　and　steady-state　spectra.　Temperature-dependent　steady-state　emission　and　decay　lifetime　indicate　that　complex　1　is　a　typical　phosphorescent　emitter.