Characterization and magnetic properties of two mixed-valence compounds A2MnⅡMn2III(SeO3)6 (A = Sr and Ba) - Details

author：

Lu, C. (Lu, C..) ^[1] | Zhang, Y. (Zhang, Y..) ^[2] | Cui, M. (Cui, M..) ^[3] | Zhao, Z. (Zhao, Z..) ^[4] | He, Z. (He, Z..) ^[5]

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Abstract：

A2MnⅡMn2III(SeO3)6　(A　=　Sr　and　Ba)　are　found　to　have　a　monoclinic　space　group　P21/c,　where　Mn3+　ions　form　a　distorted　honeycomb　lattice　centred　by　the　Mn2+　ions.　The　samples　of　two　isostructural　compounds　were　synthesized　using　a　conventional　hydrothermal　method　and　characterized　by　many　methods　including　EDS,　XRD,　FT-IR,　UV–vis　diffuse　reflectance　spectra　and　thermal　analysis.　Magnetic　measurements　confirm　that　two　compounds　display　a　similar　magnetic　behavior　with　a　short-range　and　a　long-range　antiferromagnetic　order　at　low　temperature,　while　the　metamagnetic　transition　can　be　observed　under　applied　magnetic　field.　In　addition,　the　spin-frustration　effects　of　two　compounds　are　also　investigated.　©　2023　Elsevier　B.V.

Keyword：

Hydrothermal synthesis Magnetic properties Mixed-valence Selenite

Community：

[ 1 ] [Lu C.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 2 ] [Lu C.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Zhang Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 4 ] [Zhang Y.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Cui M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 6 ] [Zhao Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 7 ] [He Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China

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Source ：

Journal of Magnetism and Magnetic Materials

ISSN： 0304-8853

Year： 2023

Volume： 586

2 . 5

JCR@2023

2 . 5 0 0

JCR@2023

JCR Journal Grade：3

CAS Journal Grade：3

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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