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author:

Lin, Min (Lin, Min.) [1] | Luo, Meilan (Luo, Meilan.) [2] | Liu, Yongzhi (Liu, Yongzhi.) [3] | Shen, Jinni (Shen, Jinni.) [4] (Scholars:沈锦妮) | Long, Jinlin (Long, Jinlin.) [5] (Scholars:龙金林) | Zhang, Zizhong (Zhang, Zizhong.) [6] (Scholars:张子重)

Indexed by:

EI Scopus SCIE CSCD

Abstract:

Constructing heterojunction is an important method to improve the performance of photocatalyst for CO2 reduction. In this work, W18O49 nanosheets (NSs) were grown on the surface of SiC nanocages (NCs) to form the sea urchin ball morphology by solvothermal method. The SiC-W18O49 composite photocatalyst processes 1D S-scheme heterojunction electron transport pathway. The special urchin morphology provides a large surface area for the contact between photocatalyst and CO2 reactants. Meantime, the S-scheme internal electric field at the heterogeneous interface of SiC-W18O49 composite photocatalyst can effectively promote the separation and migration of photogenerated carrier pairs owing to 1D heterojunction structure. The photocatalytic CO2 reduction products (CO + CH4 + CH3OH) can be produced up to 21.87 & mu;mol g-1 h-1 by SiC-W18O49 composite photocatalyst, which was 3.38 and 3.71 times of the total reduction activity of the parent SiC and W18O49, respectively. This work will provide a new idea for the design of heterojunction morphology and structure for boosting photocatalytic CO2 reduction. Published by Elsevier B.V. All rights reserved.

Keyword:

1D heterojunction CO 2 reduction Sea-urchin-structure SiC-W 18 O 49 S-scheme

Community:

  • [ 1 ] [Lin, Min]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujiang, Peoples R China
  • [ 2 ] [Luo, Meilan]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujiang, Peoples R China
  • [ 3 ] [Liu, Yongzhi]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujiang, Peoples R China
  • [ 4 ] [Shen, Jinni]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujiang, Peoples R China
  • [ 5 ] [Long, Jinlin]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujiang, Peoples R China
  • [ 6 ] [Zhang, Zizhong]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujiang, Peoples R China
  • [ 7 ] [Zhang, Zizhong]Qingyuan Innovat Lab, Quanzhou 362801, Fujiang, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2023

Volume: 50

Page: 239-248

1 5 . 7

JCR@2023

1 5 . 7 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 36

SCOPUS Cited Count: 35

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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