Metal-organic　gels　(MOGs)　emerged　as　an　attractive　luminescent　soft　material　for　electrochemiluminescence　(ECL).　In　this　work,　a　cathodic　ECL-activated　europium　metal-organic　gel　(Eu-MOG)　has　been　synthesized　by　a　facile　mixing　of　Eu3+　with　4　＇-(4-carboxyphenyl)-2,2　＇:6　＇,2　＇＇-terpyridine　(Hcptpy)　under　mild　conditions.　The　prepared　Eu-MOG　is　highly　mesoporous　for　co-reactant　permeation　to　produce　an　ultra-stable　and　high-efficient　ECL,　based　on　the　antenna　effect　of　Eu3+　coordinating　with　Hcptpy.　Moreover,　dipicolinic　acid　(DPA)　can　competitively　coordinate　with　Eu3+　instead　of　water　molecules,　producing　an　enhanced　ECL　signal.　Therefore,　an　ECL　enhancement　assay　was　developed　for　DPA　detection.　There　was　a　linear　relationship　between　the　ECL　intensity　and　the　logarithmic　concentration　of　DPA　in　the　0.01-1　mu　M　range,　and　the　detection　limit　is　7.35　nM.　This　work　displays　the　promising　application　of　Eu-MOG　in　the　ECL　field,　opening　a　broad　inspection　for　seeking　a　new　generation　of　ECL　luminophores.