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Abstract:
In this article, several novel polyesters containing renewable 2,6-pyridinedicarboxyl aromatic units are synthesized by direct polycondensation. The obtained polyesters are chemically identified by Fourier transform infrared and proton nuclear magnetic resonance. Their average weight molar masses vary with the diol chain length, from Mw = 2 600 gmol-1 to Mw = 51 600 gmol-1. These polyesters exhibit high thermal stability with thermaldegradation temperatures (Tmax) ranging from 330 to 399 degrees C. Among them, the polyesters containing bicyclic diols (isosorbide IS and isomannide IM) are amorphous and show glass transition temperatures (Tg) up to 163 degrees C and 176 degrees C respectively. Besides, polyesters containing linear diols are semi-crystalline with melting temperatures (Tm) ranging from 110 to 189 degrees C. The semi-crystalline nature is verified by X-ray diffraction and polarized optical microscopy. These results disclose that 2,6-pyridinedicarboxylic acid (PDA26) is attractive as a bio-occuring molecule for preparing both high Tg and semi-crystalline polymers when finely choosing the diols.
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JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
ISSN: 1060-1325
Year: 2024
Issue: 2
Volume: 62
Page: 126-134
2 . 1 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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