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author:

Cao, Junwen (Cao, Junwen.) [1] | Zheng, Yun (Zheng, Yun.) [2] (Scholars:郑云) | Zhang, Wenqiang (Zhang, Wenqiang.) [3] | Yu, Bo (Yu, Bo.) [4]

Indexed by:

EI Scopus SCIE CSCD

Abstract:

Interconnector is a critical component to construct solid oxide cells (SOCs) stack. Oxidation of metallic interconnectors and Cr poisoning caused by oxidation are important factors that lead to long-term performance degradation of SOCs. Coating on the interconnector surface is an important approach to inhibit the oxidation and Cr migration of the interconnector. Herein, (La0.75Sr0.25)0.95MnO3-delta (LSM) and Mn1.5Co1.5O4 (MCO) are used to fabricate the coatings of interconnector. Two advanced thermal spray technology, atmospheric plasma spraying (APS) and low-pressure plasma spray (LPPS), are adopted for the coating preparation. The electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition performance of the coatings are tested and evaluated. The result indicates that MCO can generate more uniform and denser coatings than LSM. In addition, MCO coatings prepared by LPPS shows the best electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition. The initial area specific resistance (ASR) is 0.0027 omega center dot cm2 at 800 degrees C. After 4 cooling cycle tests, the ASR increases to 0.0032 omega center dot cm2 but lower than other samples. Meanwhile, the relative intense of Cr at the interface of SUS430 with MCO coatings fabricated by LPPS is lower than that of MCO fabricated by APS after 4 rising and cooling cycle operations, showing more favorable Cr diffusion inhibition performance.

Keyword:

Cr diffusion inhibition electrochemical performance interconnector coating plasma spray solid oxide cells (SOCs)

Community:

  • [ 1 ] [Cao, Junwen]Tsinghua Univ, Inst Nucl & New Energy Technol INET, Collaborat Innovat Ctr Adv Nucl Energy Technol, Beijing 100084, Peoples R China
  • [ 2 ] [Zhang, Wenqiang]Tsinghua Univ, Inst Nucl & New Energy Technol INET, Collaborat Innovat Ctr Adv Nucl Energy Technol, Beijing 100084, Peoples R China
  • [ 3 ] [Yu, Bo]Tsinghua Univ, Inst Nucl & New Energy Technol INET, Collaborat Innovat Ctr Adv Nucl Energy Technol, Beijing 100084, Peoples R China
  • [ 4 ] [Zheng, Yun]Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada
  • [ 5 ] [Zheng, Yun]Fuzhou Univ, Inst New Energy Mat & Engn, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China

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Source :

FRONTIERS IN ENERGY

ISSN: 2095-1701

Year: 2023

Issue: 3

Volume: 18

Page: 390-398

3 . 1

JCR@2023

3 . 1 0 0

JCR@2023

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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