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In this work, to systematically investigate the evolution characteristics of electrical properties in polymorphic piezoceramics, the Ba(Ti0.92Zr0.08)O-3 ceramics are selected as a paradigm that possesses all the general phase structures above room temperature. It is found that the evolution of electrical properties with temperature change can be divided into three stages based on phase structure transforming: high ferroelectric and stable strain properties at R and R-O, high ferroelectric and enhanced strain/converse piezoelectric properties at O, O-T, and T phase, and the rapidly decreased ferroelectric and strain properties in T-C and C phase. However, the ferroelectric and strain properties all increase with rising electric field and their evolution can be divided into two parts based on phase structures. The high property and slow increase rate are present at R, R-O, O, and O-T, while the poor property but a high increase rate is present around T-C. Similar results can be found in the evolution of electrostrictive property. Finally, the highest d(33)* of similar to 1240 pm/V and Q(33) of similar to 0.053 m(4)/C-2 are obtained at O-T due to the high ferroelectricity but easy domain switching. This work affords important guidance for the property optimization of polymorphic piezoceramics.
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CRYSTALS
ISSN: 2073-4352
Year: 2023
Issue: 9
Volume: 13
2 . 4
JCR@2023
2 . 4 0 0
JCR@2023
JCR Journal Grade:2
CAS Journal Grade:3
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WoS CC Cited Count: 0
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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