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author:

Tao, Y. (Tao, Y..) [1] | Fan, G. (Fan, G..) [2] | Li, X. (Li, X..) [3] | Cao, X. (Cao, X..) [4] | Du, B. (Du, B..) [5] | Li, H. (Li, H..) [6] | Luo, J. (Luo, J..) [7] | Hong, Z. (Hong, Z..) [8] | Xu, K.-Q. (Xu, K.-Q..) [9]

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Scopus

Abstract:

In order to effectively curb the various hazards posed by carbamazepine (CBZ) to aquatic ecosystems, a recyclable magnetic AgBr/BiOBr/Fe3O4 composite photocatalytic material was successfully synthesized in this study. When the content of Fe3O4 was 5 wt% (ABF-5), the ABF-5/Vis/PMS system was formed under peroxymonosulfate (PMS) and visible light (Vis). The system was able to degrade 96.84 % of CBZ within 30 min, with good photocatalytic synergy and degradation effect. Meanwhile, the system also showed a satisfactory degradation effect on CBZ in real water bodies such as reservoir water and hospital wastewater. In the ABF-5/Vis/PMS system, CBZ was degraded mainly by cleavage, hydroxylation, oxidation, and decarboxylation, and the active substances such as 1O2, [rad]O2−, h+ played a major role in the degradation process. After five cycles of experiments, the degradation efficiency of CBZ remained above 85 %. Moreover, ABF-5 can be quickly separated and easily reused under an external magnetic field with good stability. In summary, the recoverable magnetic ABF-5 has good potential for practical application and could provide novel perspectives methods, and ideas for the treatment of persistent organic pollutants treatment in water ecosystems. © 2023 Elsevier B.V.

Keyword:

Carbamazepine Degradation mechanisms Magnetic catalyst Peroxymonosulfate Photocatalysis

Community:

  • [ 1 ] [Tao Y.]College of Civil Engineering, Fuzhou University, Fujian, 350116, China
  • [ 2 ] [Fan G.]College of Civil Engineering, Fuzhou University, Fujian, 350116, China
  • [ 3 ] [Fan G.]Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Fujian, 350002, China
  • [ 4 ] [Li X.]College of Civil Engineering, Fuzhou University, Fujian, 350116, China
  • [ 5 ] [Cao X.]College of Civil Engineering, Fuzhou University, Fujian, 350116, China
  • [ 6 ] [Du B.]College of Civil Engineering, Fuzhou University, Fujian, 350116, China
  • [ 7 ] [Li H.]College of Civil Engineering, Fuzhou University, Fujian, 350116, China
  • [ 8 ] [Li H.]Fuzhou City Construction Design & Research Institute Co. Ltd., Fujian, 350001, China
  • [ 9 ] [Luo J.]Fujian Jinhuang Environmental Sci-Tech Co., Ltd., Fujian, 350002, China
  • [ 10 ] [Hong Z.]China Construction Third Bureau First Engineering Co. Ltd., Hubei, 430040, China
  • [ 11 ] [Xu K.-Q.]College of Civil Engineering, Fuzhou University, Fujian, 350116, China

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Source :

Separation and Purification Technology

ISSN: 1383-5866

Year: 2024

Volume: 330

8 . 2 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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