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author:

Tao, Yang (Tao, Yang.) [1] | Fan, Gongduan (Fan, Gongduan.) [2] (Scholars:范功端) | Li, Xia (Li, Xia.) [3] | Cao, Xingfeng (Cao, Xingfeng.) [4] | Du, Banghao (Du, Banghao.) [5] | Li, Hao (Li, Hao.) [6] | Luo, Jing (Luo, Jing.) [7] | Hong, Zhanglin (Hong, Zhanglin.) [8] | Xu, Kai-Qin (Xu, Kai-Qin.) [9]

Indexed by:

EI Scopus SCIE

Abstract:

In order to effectively curb the various hazards posed by carbamazepine (CBZ) to aquatic ecosystems, a recyclable magnetic AgBr/BiOBr/Fe3O4 composite photocatalytic material was successfully synthesized in this study. When the content of Fe3O4 was 5 wt% (ABF-5), the ABF-5/Vis/PMS system was formed under peroxymonosulfate (PMS) and visible light (Vis). The system was able to degrade 96.84 % of CBZ within 30 min, with good photocatalytic synergy and degradation effect. Meanwhile, the system also showed a satisfactory degradation effect on CBZ in real water bodies such as reservoir water and hospital wastewater. In the ABF-5/Vis/PMS system, CBZ was degraded mainly by cleavage, hydroxylation, oxidation, and decarboxylation, and the active substances such as O-1(2), O-center dot(2)-, h(+) played a major role in the degradation process. After five cycles of experiments, the degradation efficiency of CBZ remained above 85 %. Moreover, ABF-5 can be quickly separated and easily reused under an external magnetic field with good stability. In summary, the recoverable magnetic ABF-5 has good potential for practical application and could provide novel perspectives methods, and ideas for the treatment of persistent organic pollutants treatment in water ecosystems.

Keyword:

Carbamazepine Degradation mechanisms Magnetic catalyst Peroxymonosulfate Photocatalysis

Community:

  • [ 1 ] [Tao, Yang]Fuzhou Univ, Coll Civil Engn, Fujian 350116, Peoples R China
  • [ 2 ] [Fan, Gongduan]Fuzhou Univ, Coll Civil Engn, Fujian 350116, Peoples R China
  • [ 3 ] [Li, Xia]Fuzhou Univ, Coll Civil Engn, Fujian 350116, Peoples R China
  • [ 4 ] [Cao, Xingfeng]Fuzhou Univ, Coll Civil Engn, Fujian 350116, Peoples R China
  • [ 5 ] [Du, Banghao]Fuzhou Univ, Coll Civil Engn, Fujian 350116, Peoples R China
  • [ 6 ] [Li, Hao]Fuzhou Univ, Coll Civil Engn, Fujian 350116, Peoples R China
  • [ 7 ] [Xu, Kai-Qin]Fuzhou Univ, Coll Civil Engn, Fujian 350116, Peoples R China
  • [ 8 ] [Fan, Gongduan]Fuzhou Univ, Fujian Prov Key Lab Electrochem Energy Storage Mat, Fujian 350002, Peoples R China
  • [ 9 ] [Li, Hao]Fuzhou City Construct Design & Res Inst Co Ltd, Fujian 350001, Peoples R China
  • [ 10 ] [Luo, Jing]Fujian Jinhuang Environm Scitech Co Ltd, Fujian 350002, Peoples R China
  • [ 11 ] [Hong, Zhanglin]China Construct Third Bur First Engn Co Ltd, Wuhan 430040, Hubei, Peoples R China

Reprint 's Address:

  • [Fan, Gongduan]Fuzhou Univ, Coll Civil Engn, Fujian 350116, Peoples R China;;

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2023

Volume: 330

8 . 2

JCR@2023

8 . 2 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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