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author:

Cai, J. (Cai, J..) [1] | Chen, X. (Chen, X..) [2] | Zhang, W. (Zhang, W..) [3] | Yang, L. (Yang, L..) [4] | Lin, Z. (Lin, Z..) [5] | Zhao, W. (Zhao, W..) [6] | Ye, Y. (Ye, Y..) [7] | Xu, S. (Xu, S..) [8] | Guo, T. (Guo, T..) [9] | Chen, E. (Chen, E..) [10]

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Scopus

Abstract:

Owing to their composition-tunable and narrow emissions and high photoluminescence quantum yield (PLQY), inorganic halide perovskite quantum dots (IPQDs) are a promising option for wide color gamut displays. However, their practical applications have been limited by their lattice structure instability and surface defect states. Herein, CsPbBr3:KBF4@SiO2 with improved stability and optical properties is successfully synthesized with a two-step optimization of fluorine (F) anion doping and SiO2 in situ coating. Compared with bromide (Br), higher electronegativity and a smaller radius of F lead to stronger binding energy with Pb2+. Also, F anions can occupy surface Br vacancies. Then, benefiting from the acidic environment provided by BF4− hydrolysis, tetraethyl orthosilicate (TEOS) can be more easily hydrolyzed on the CsPbBr3:KBF4 surface to generate SiO2 coating, thus further passivating lattice defects and improving environmental stability. Importantly, the PLQY of CsPbBr3:KBF4@SiO2 achieves 85%, and the stability has been greatly improved compared with pure CsPbBr3. Finally, CsPbBr3:KBF4@SiO2/PDMS, CsPbI3/PDMS, and CsPbCl3/PDMS composites with narrow emissions are applied to replace traditional phosphors as color converters for direct-view light-emitting diode (LED) displays or liquid crystal display (LCD) backlights. The color gamut reaches 118.22% under the NTSC standard. Concerning the display field, it suggests likely applications in the future. © 2023 by the authors.

Keyword:

CsPbBr3 KBF4 LED displays liquid crystal displays SiO2 wide color gamut

Community:

  • [ 1 ] [Cai J.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Chen X.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Zhang W.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Yang L.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Lin Z.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 6 ] [Zhao W.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Ye Y.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 8 ] [Ye Y.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 9 ] [Xu S.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 10 ] [Xu S.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 11 ] [Guo T.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 12 ] [Guo T.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 13 ] [Chen E.]National & Local United Engineer Laboratory of Flat Panel Display Technology, College of Physics and Information Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 14 ] [Chen E.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China

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Source :

Photonics

ISSN: 2304-6732

Year: 2023

Issue: 10

Volume: 10

2 . 1

JCR@2023

2 . 1 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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