• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Ng, Zhi Kai (Ng, Zhi Kai.) [1] | Li, Bing (Li, Bing.) [2] | Zhu, Minmin (Zhu, Minmin.) [3] (Scholars:朱敏敏) | Du, Zehui (Du, Zehui.) [4] | Zhao, Yida (Zhao, Yida.) [5] | Chng, Soon Siang (Chng, Soon Siang.) [6] | Li, Hongling (Li, Hongling.) [7] | Tay, Roland Yingjie (Tay, Roland Yingjie.) [8] | Tsang, Siu Hon (Tsang, Siu Hon.) [9] | Teo, Edwin Hang Tong (Teo, Edwin Hang Tong.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

Hybrid Zn-Air and Zn-MX (MX refers to metal species with cation redox properties) batteries that combine the merits of both types are attracting increasing interest. However, the low areal capacity of the Zn-MX segment hinders their applications toward power resilience. Increasing the electrochemically active material loading is critical to achieving sufficient capacity but poses a challenge for conventional electrodes to maintain fast gas diffusion, which is necessary for the Zn-air function. Herein, we report an advanced, monolithic, carbon-based current collector by growing carbon nanotubes (CNT) onto a 3D graphene network (3DGF). The porous and highly conductive current collector readily accommodates more electrochemically active material, NiCo2O4 (NCO), thereby improving the Zn-NCO segment's capacity without sacrificing the Zn-air segment's performance. The 3DGF/CNT/NCO electrode was fabricated into a hybrid Zn battery which achieved a superior areal specific capacity of 2.87 mAh cm-2 at 5 mA cm-2, almost threefold of previously reported values, and an impressive rate capability and cycling stability with 98% of original capacity retained after 1000 cycles at 20 mA cm-2 charging/discharging current density. This work showcases 3DGF/CNT as an advanced current collector architecture for new and novel batteries.

Keyword:

Carbon nanotubes Electrode engineering Graphene foam Zinc hybrid batteries

Community:

  • [ 1 ] [Ng, Zhi Kai]Nanyang Technol Univ, Sch Elect & Elect Engn, 50 Nanyang Ave, Singapore 639798, Singapore
  • [ 2 ] [Chng, Soon Siang]Nanyang Technol Univ, Sch Elect & Elect Engn, 50 Nanyang Ave, Singapore 639798, Singapore
  • [ 3 ] [Li, Hongling]Nanyang Technol Univ, Sch Elect & Elect Engn, 50 Nanyang Ave, Singapore 639798, Singapore
  • [ 4 ] [Tay, Roland Yingjie]Nanyang Technol Univ, Sch Elect & Elect Engn, 50 Nanyang Ave, Singapore 639798, Singapore
  • [ 5 ] [Tsang, Siu Hon]Nanyang Technol Univ, Sch Elect & Elect Engn, 50 Nanyang Ave, Singapore 639798, Singapore
  • [ 6 ] [Teo, Edwin Hang Tong]Nanyang Technol Univ, Sch Elect & Elect Engn, 50 Nanyang Ave, Singapore 639798, Singapore
  • [ 7 ] [Li, Bing]ASTAR, Inst Mat Res & Engn IMRE, 2 Fusionopolis Way,Innovis 08-03, Singapore 138634, Singapore
  • [ 8 ] [Zhu, Minmin]Fuzhou Univ, Coll Phys & Informat Engn, Wulongjiang Ave, Fuzhou 350116, Fujian, Peoples R China
  • [ 9 ] [Du, Zehui]Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
  • [ 10 ] [Zhao, Yida]Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
  • [ 11 ] [Teo, Edwin Hang Tong]Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

Reprint 's Address:

Show more details

Related Keywords:

Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2023

Volume: 477

1 3 . 4

JCR@2023

1 3 . 4 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

Online/Total:789/10851720
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1