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author:

Ding, Yinxuan (Ding, Yinxuan.) [1] | Zhang, Long (Zhang, Long.) [2] | Gao, Xinglong (Gao, Xinglong.) [3] | Wei, Mingzhi (Wei, Mingzhi.) [4] | Liu, Qu (Liu, Qu.) [5] | Li, Yunbiao (Li, Yunbiao.) [6] | Li, Zhen (Li, Zhen.) [7] | Cheng, Lingli (Cheng, Lingli.) [8] | Wu, Minghong (Wu, Minghong.) [9] (Scholars:吴明红)

Indexed by:

SCIE

Abstract:

Transition metal selenides are considered as promising anode materials for potassium-ion batteries (PIBs) due to their high theoretical capacities. However, their applications are limited by low conductivity and large volume expansion. Herein, sugar-gourd-shaped carbon nanofibers embedded with heterostructured ZnCo-Se nanocages are prepared via a facile template-engaged method combined with electrospinning and selenization process. In this hierarchical ZnCo-Se@NC/CNF, abundant phase boundaries of CoSe2/ZnSe heterostructure can promote interfacial electron transfer and chemical reactivity. The interior porous ZnCo-Se@NC nanocage structure relieves volume expansion and maintains structural integrity during K+ intercalation and deintercalation. The exterior spinning carbon nanofibers connect the granular nanocages in series, which prevents the agglomeration, shortens the electron transport distance and enhances the reaction kinetics. As a self-supporting anode material, ZnCo-Se@NC/CNF delivers a high capacity (362 mA h g-1 at 0.1 A g-1 after 100 cycles) with long-term stability (95.9% capacity retention after 1000 cycles) and shows superior reaction kinetics with high-rate K-storage. Energy level analysis and DFT calculations illustrate heterostructure facilitates the adsorption of K+ and interfacial electron transfer. The K+ storage mechanism is revealed by ex situ XRD and EIS analyses. This work opens a novel avenue in designing high-performance heterostructured anode materials with ingenious structure for PIBs. Sugar-gourd-shaped carbon nanofibers embedded with heterostructured ZnCo-Se nanocages are prepared via a facile template-engaged method combined with electrospinning and selenization process. Benefiting from interfacial effects of the CoSe2/ZnSe heterostructure, rapid K+ diffusion of hollow porous nanocage structure, and shortened multiple electron transport channels of spun carbon nanofibers, ZnCo-Se@NC/CNF as a self-supporting anode material exhibits excellent potassium storage performance.image

Keyword:

carbon nanofibers heterostructure potassium-ion storage self-supporting anode zinc-cobalt selenide

Community:

  • [ 1 ] [Ding, Yinxuan]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 2 ] [Zhang, Long]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 3 ] [Gao, Xinglong]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 4 ] [Liu, Qu]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 5 ] [Li, Yunbiao]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 6 ] [Li, Zhen]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 7 ] [Wei, Mingzhi]Qilu Univ Technol, Sch Mat Sci & Engn, Jinan 250353, Peoples R China
  • [ 8 ] [Cheng, Lingli]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201800, Peoples R China
  • [ 9 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201800, Peoples R China

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ISSN: 1613-6810

Year: 2023

1 3 . 0

JCR@2023

1 3 . 0 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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