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author:

Yao, Jie (Yao, Jie.) [1] | Zhang, Chenglin (Zhang, Chenglin.) [2] | Yang, Guowei (Yang, Guowei.) [3] | Sha, Mo (Sha, Mo.) [4] | Dong, Yulian (Dong, Yulian.) [5] | Fu, Qun (Fu, Qun.) [6] | Wu, Yuhan (Wu, Yuhan.) [7] | Zhao, Huaping (Zhao, Huaping.) [8] | Wu, Minghong (Wu, Minghong.) [9] (Scholars:吴明红) | Lei, Yong (Lei, Yong.) [10]

Indexed by:

SCIE

Abstract:

Bismuth (Bi) has been considered as a promising alloyingtype anode for potassium-ion batteries (PIBs), owing to its high theoretical capacity and suitable working voltage plateaus. However, Bi suffers from dramatic volume fluctuation and significant pulverization during the discharge/charge processes, resulting in fast capacity decay. Herein, we synthesize Bi nanoparticles confined in carbonaceous nanospheres (denoted as Bi@C) for PIBs by first utilizing BiOCl nanoflakes as a hard template and a Bi precursor. The construction of the loose structure buffers the mechanical stresses resulting from the volume expansion of Bi during the alloying reaction and avoids the fracture of the electrode structure, thus improving the cycling performance. Moreover, the carbonaceous layers increase the electronic conductivity and disperse the Bi nanoparticles, enhancing the charge transportation and ionic diffusion, which further promotes the rate capability of Bi@C. It exhibits a superior capacity (389 mAh g(-1) at 100 mA g(-1) after 100 cycles), excellent cycling stability (206 mAh g(-1) at 500 mA g(-1) over 1000 cycles), and an improved rate capability (182 mAh g(-1) at 2.0 A g(-1)). This work provides a new structuring strategy in alloying materials for boosting reversible and stable potassium-ion storage.

Keyword:

BiOCl bismuth carbonaceous nanospheres nanoparticles potassium-ion batteries

Community:

  • [ 1 ] [Yao, Jie]Shanghai Univ, Sch Environm & Chem Engn, Inst Nanochem & Nano Biol, Shanghai 200444, Peoples R China
  • [ 2 ] [Yang, Guowei]Shanghai Univ, Sch Environm & Chem Engn, Inst Nanochem & Nano Biol, Shanghai 200444, Peoples R China
  • [ 3 ] [Fu, Qun]Shanghai Univ, Sch Environm & Chem Engn, Inst Nanochem & Nano Biol, Shanghai 200444, Peoples R China
  • [ 4 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Inst Nanochem & Nano Biol, Shanghai 200444, Peoples R China
  • [ 5 ] [Zhang, Chenglin]Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
  • [ 6 ] [Sha, Mo]Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
  • [ 7 ] [Dong, Yulian]Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
  • [ 8 ] [Wu, Yuhan]Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
  • [ 9 ] [Zhao, Huaping]Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
  • [ 10 ] [Lei, Yong]Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
  • [ 11 ] [Zhang, Chenglin]Tech Univ Ilmenau, IMN MacroNano ZIK, D-98693 Ilmenau, Germany
  • [ 12 ] [Sha, Mo]Tech Univ Ilmenau, IMN MacroNano ZIK, D-98693 Ilmenau, Germany
  • [ 13 ] [Dong, Yulian]Tech Univ Ilmenau, IMN MacroNano ZIK, D-98693 Ilmenau, Germany
  • [ 14 ] [Wu, Yuhan]Tech Univ Ilmenau, IMN MacroNano ZIK, D-98693 Ilmenau, Germany
  • [ 15 ] [Zhao, Huaping]Tech Univ Ilmenau, IMN MacroNano ZIK, D-98693 Ilmenau, Germany
  • [ 16 ] [Lei, Yong]Tech Univ Ilmenau, IMN MacroNano ZIK, D-98693 Ilmenau, Germany

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2021

Issue: 27

Volume: 13

Page: 31766-31774

1 0 . 3 8 3

JCR@2021

8 . 5 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 40

SCOPUS Cited Count: 39

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

Affiliated Colleges:

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