All-solid-state　asymmetric　supercapacitors　with　flexible　electrode　materials　have　been　widely　applied　in　wearable　electronic　devices.　Herein,　hierarchical　and　porous　carbon　nanofibers　(CNF)　embedded　with　MOF-derived　N-doped　porous　carbon　(NPC)　nanoparticles　and　decorated　with　ZnO　quantum　dots　(ZnO　QDs)　are　fabricated　by　co-electrospinning　and　carbonization　processes.　In　the　as-prepared　ZnO　QD/NPC/CNF　composite,　the　embedding　of　NPC　nanoparticles　greatly　improves　the　specific　surface　area　and　the　conductivity　of　carbon　nanofibers　to　accelerate　the　electron　transfer　and　stabilize　the　mechanical　structure　of　carbon　nanofibers,　while　the　addition　of　ZnO　QDs　provides　abundant　pseudo-capacitive　active　sites.　As　a　result,　the　ZnO　QD/NPC/CNF　electrode　as　a　self-supporting　and　binder-free　positive　electrode　exhibits　a　high　specific　capacity　of　71.6　mA　h　g(-1)　(644.4　F　g(-1))　at　1　A　g(-1).　Based　on　a　＂one　for　two＂　strategy,　the　NPC/CNF　as　a　negative　electrode　material　is　simply　prepared　by　etching　the　positive　electrode　with　acid.　The　assembled　flexible　all-solid-state　asymmetric　supercapacitor　achieves　a　high　energy　density　of　33.8　W　h　kg(-1)　at　a　power　density　of　800　W　kg(-1),　excellent　mechanical　flexibility　and　cycling　stability　(83.1%　of　the　initial　capacity　after　5000　cycles).　The　rational　design　of　this　work　provides　an　effective　way　to　construct　a　new　electrode　material　of　a　high-performance　energy　storage　system　for　wearable　electronic　devices.