Covalent　organic　frameworks　(COF)　or　metal-organic　frameworks　have　attracted　significant　attention　for　various　applications　due　to　their　intriguing　tunable　micro/mesopores　and　composition/functionality　control.　Herein,　a　coordination-induced　interlinked　hybrid　of　imine-based　covalent　organic　frameworks　and　Mn-based　metal-organic　frameworks　(COF/Mn-MOF)　based　on　the　Mn　-　N　bond　is　reported.　The　effective　molecular-level　coordination-induced　compositing　of　COF　and　MOF　endows　the　hybrid　with　unique　flower-like　microsphere　morphology　and　superior　lithium-storage　performances　that　originate　from　activated　Mn　centers　and　the　aromatic　benzene　ring.　In　addition,　hollow　or　core-shell　MnS　trapped　in　N　and　S　codoped　carbon　(MnS@NS-C-g　and　MnS@NS-C-l)　are　also　derived　from　the　COF/Mn-MOF　hybrid　and　they　exhibit　good　lithium-storage　properties.　The　design　strategy　of　COF-MOF　hybrid　can　shed　light　on　the　promising　hybridization　on　porous　organic　framework　composites　with　molecular-level　structural　adjustment,　nano/microsized　morphology　design,　and　property　optimization.