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author:

Zhan, Jing (Zhan, Jing.) [1] | Wu, Kuan (Wu, Kuan.) [2] | Yu, Xue (Yu, Xue.) [3] | Yang, Mengjia (Yang, Mengjia.) [4] | Cao, Xu (Cao, Xu.) [5] | Lei, Bo (Lei, Bo.) [6] | Pan, Dengyu (Pan, Dengyu.) [7] | Jiang, Hu (Jiang, Hu.) [8] | Wu, Minghong (Wu, Minghong.) [9] (Scholars:吴明红)

Indexed by:

SCIE

Abstract:

MoS2 nanosheets as a promising 2D nanomaterial have extensive applications in energy storage and conversion, but their electrochemical performance is still unsatisfactory as an anode for efficient Li+/Na+ storage. In this work, the design and synthesis of vertically grown MoS2 nanosheet arrays, decorated with graphite carbon and Fe2O3 nanoparticles, on flexible carbon fiber cloth (denoted as Fe2O3@C@MoS2/CFC) is reported. When evaluated as an anode for lithium-ion batteries, the Fe2O3@C@MoS2/CFC electrode manifests an outstanding electrochemical performance with a high discharge capacity of 1541.2 mAh g(-1) at 0.1 A g(-1) and a good capacity retention of 80.1% at 1.0 A g(-1) after 500 cycles. As for sodium-ion batteries, it retains a high reversible capacity of 889.4 mAh g(-1) at 0.5 A g(-1) over 200 cycles. The superior electrochemical performance mainly results from the unique 3D ordered Fe2O3@C@MoS2 array-type nanostructures and the synergistic effect between the C@MoS2 nanosheet arrays and Fe2O3 nanoparticles. The Fe2O3 nanoparticles act as spacers to steady the structure, and the graphite carbon could be incorporated into MoS2 nanosheets to improve the conductivity of the whole electrode and strengthen the integration of MoS2 nanosheets and CFC by the adhesive role, together ensuring high conductivity and mechanical stability.

Keyword:

electrochemistry Fe2O3 nanoparticles graphite C interlayer-expanded MoS2 Li+/Na+ storage

Community:

  • [ 1 ] [Zhan, Jing]Shanghai Univ, Sch Environm & Chem Engn, 99 Shangda Rd, Shanghai 200444, Peoples R China
  • [ 2 ] [Wu, Kuan]Shanghai Univ, Sch Environm & Chem Engn, 99 Shangda Rd, Shanghai 200444, Peoples R China
  • [ 3 ] [Yu, Xue]Shanghai Univ, Sch Environm & Chem Engn, 99 Shangda Rd, Shanghai 200444, Peoples R China
  • [ 4 ] [Yang, Mengjia]Shanghai Univ, Sch Environm & Chem Engn, 99 Shangda Rd, Shanghai 200444, Peoples R China
  • [ 5 ] [Cao, Xu]Shanghai Univ, Sch Environm & Chem Engn, 99 Shangda Rd, Shanghai 200444, Peoples R China
  • [ 6 ] [Lei, Bo]Shanghai Univ, Sch Environm & Chem Engn, 99 Shangda Rd, Shanghai 200444, Peoples R China
  • [ 7 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, 99 Shangda Rd, Shanghai 200444, Peoples R China
  • [ 8 ] [Zhan, Jing]Natl Univ Singapore, Grad Sch Integrat Sci & Engn, Singapore 117583, Singapore
  • [ 9 ] [Pan, Dengyu]Shanghai Univ, Sch Environm & Chem Engn, Dept Chem Engn, Shanghai 200444, Peoples R China
  • [ 10 ] [Jiang, Hu]Shanghai Univ, Sch Mat Sci & Engn, 99 Shangda Rd, Shanghai 200444, Peoples R China

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Source :

SMALL

ISSN: 1613-6810

Year: 2019

Issue: 21

Volume: 15

1 1 . 4 5 9

JCR@2019

1 3 . 0 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 73

SCOPUS Cited Count: 67

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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