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author:

Wu, Ling (Wu, Ling.) [1] | Zheng, Jie (Zheng, Jie.) [2] | Wang, Liang (Wang, Liang.) [3] | Xiong, Xunhui (Xiong, Xunhui.) [4] | Shao, Yanyan (Shao, Yanyan.) [5] | Wang, Gang (Wang, Gang.) [6] | Wang, Jeng-Han (Wang, Jeng-Han.) [7] | Zhong, Shengkui (Zhong, Shengkui.) [8] | Wu, Minghong (Wu, Minghong.) [9] (Scholars:吴明红)

Indexed by:

SCIE

Abstract:

Nanostructured-alloy-type anodes have received great interest for high-performance lithium-ion batteries (LIBs). However, these anodes experience huge volume fluctuations during repeated lithiation/delithiation and are easily pulverized and subsequently form aggregates. Herein, an efficient method to stabilize alloy-type anodes by creating defects on the surface of the metal oxide support is proposed. As a demonstration, PPy-encapsulated SnS2 nanosheets supported on defect-rich TiO2 nanotubes were produced and investigated as an anode material for LIBs. Both experimental results and theoretical calculations demonstrate that defect-rich TiO2 provides more chemical adhesions to SnS2 and discharge products, compared to defect-poor TiO2, and then effectively stabilizes the electrode structure. As a result, the composite exhibits an unprecedented cycle stability. This work paves the way to designing durable and active nanostructured-alloy-type anodes on oxide supports.

Keyword:

cycle stability lithium-ion battery oxygen defect SnS2 anode TiO2 support

Community:

  • [ 1 ] [Wu, Ling]Soochow Univ, Sch Iron & Steel, Suzhou 215021, Peoples R China
  • [ 2 ] [Zhong, Shengkui]Soochow Univ, Sch Iron & Steel, Suzhou 215021, Peoples R China
  • [ 3 ] [Zheng, Jie]South China Univ Technol, Guangzhou Key Lab Surface Chem Energy Mat, New Energy Res Inst, Sch Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China
  • [ 4 ] [Xiong, Xunhui]South China Univ Technol, Guangzhou Key Lab Surface Chem Energy Mat, New Energy Res Inst, Sch Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China
  • [ 5 ] [Wang, Gang]South China Univ Technol, Guangzhou Key Lab Surface Chem Energy Mat, New Energy Res Inst, Sch Environm & Energy, Guangzhou 510006, Guangdong, Peoples R China
  • [ 6 ] [Wang, Liang]Shanghai Univ, Inst Nanochem & Nanobiol, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 7 ] [Wu, Minghong]Shanghai Univ, Inst Nanochem & Nanobiol, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 8 ] [Shao, Yanyan]Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan
  • [ 9 ] [Wang, Jeng-Han]Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan

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Source :

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN: 1433-7851

Year: 2019

Issue: 3

Volume: 58

Page: 811-815

1 2 . 9 5 9

JCR@2019

1 6 . 1 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 283

SCOPUS Cited Count: 282

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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