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An original electrode, 3D TiO2@C core/shell nanobelt arrays with controllable carbon coating thickness, was successfully constructed in this work. The 3D TiO2 nanobelts were directly grown on Ti foil, and then were coated with a layer of metal-organic framework (MOF). After thermal annealing, a porous carbon layer with tunable thickness was coated onto the 3D TiO2 nanobelts through changing the MOF thickness. The as-prepared TiO2@C-2 h with 5-nm-thick carbon layer presented an excellent discharge capacity of 210.5 mAh g(-1) after 100 cycles at a current density of 50 mA g(-1), which is 38% higher than that of pure TiO2 electrode without carbon coating. Moreover, it can maintain a reversible capacity of 141 mAh g(-1) after 1000 cycles at a current density of 200 mA g(-1), and a good rate performance with 33% of capacity retention when the current density increasing from 50 to 5000 mA g(-1). All the results indicate that the TiO2@C core/shell nanobelt array is a promising anode for sodium-ion batteries. (C) 2018 Elsevier B.V. All rights reserved.
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JOURNAL OF ALLOYS AND COMPOUNDS
ISSN: 0925-8388
Year: 2018
Volume: 769
Page: 257-263
4 . 1 7 5
JCR@2018
5 . 8 0 0
JCR@2023
JCR Journal Grade:1
CAS Journal Grade:1
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ESI Highly Cited Papers on the List: 0 Unfold All
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Chinese Cited Count:
30 Days PV: 4
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