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Abstract:
Potassium-ion batteries are a promising alternative to lithium-ion batteries. However, it is challenging to achieve fast charging/discharging and long cycle life with the current electrode materials because of the sluggish potassiation kinetics. Here we report a soft carbon anode, namely highly nitrogen-doped carbon nanofibers, with superior rate capability and cyclability. The anode delivers reversible capacities of 248 mAh g(-1) at 25 mA g(-1) and 101 mAh g(-1) at 20 A g(-1), and retains 146 mAh g(-1) at 2 A g(-1) after 4000 cycles. Surface-dominated K-storage is verified by quantitative kinetics analysis and theoretical investigation. A full cell coupling the anode and Prussian blue cathode delivers a reversible capacity of 195 mAh g(-1) at 0.2 A g(-1). Considering the cost-effectiveness and material sustainability, our work may shed some light on searching for K-storage materials with high performance.
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Source :
NATURE COMMUNICATIONS
ISSN: 2041-1723
Year: 2018
Volume: 9
1 1 . 8 7 8
JCR@2018
1 4 . 7 0 0
JCR@2023
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 941
SCOPUS Cited Count: 952
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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