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author:

Xu, Yang (Xu, Yang.) [1] | Zhang, Chenglin (Zhang, Chenglin.) [2] | Zhou, Min (Zhou, Min.) [3] | Fu, Qun (Fu, Qun.) [4] | Zhao, Chengxi (Zhao, Chengxi.) [5] | Wu, Minghong (Wu, Minghong.) [6] (Scholars:吴明红) | Lei, Yong (Lei, Yong.) [7]

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SCIE

Abstract:

Potassium-ion batteries are a promising alternative to lithium-ion batteries. However, it is challenging to achieve fast charging/discharging and long cycle life with the current electrode materials because of the sluggish potassiation kinetics. Here we report a soft carbon anode, namely highly nitrogen-doped carbon nanofibers, with superior rate capability and cyclability. The anode delivers reversible capacities of 248 mAh g(-1) at 25 mA g(-1) and 101 mAh g(-1) at 20 A g(-1), and retains 146 mAh g(-1) at 2 A g(-1) after 4000 cycles. Surface-dominated K-storage is verified by quantitative kinetics analysis and theoretical investigation. A full cell coupling the anode and Prussian blue cathode delivers a reversible capacity of 195 mAh g(-1) at 0.2 A g(-1). Considering the cost-effectiveness and material sustainability, our work may shed some light on searching for K-storage materials with high performance.

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Community:

  • [ 1 ] [Xu, Yang]Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
  • [ 2 ] [Zhou, Min]Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
  • [ 3 ] [Lei, Yong]Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
  • [ 4 ] [Xu, Yang]Tech Univ Ilmenau, IMN MacroNano ZIK, D-98693 Ilmenau, Germany
  • [ 5 ] [Zhou, Min]Tech Univ Ilmenau, IMN MacroNano ZIK, D-98693 Ilmenau, Germany
  • [ 6 ] [Lei, Yong]Tech Univ Ilmenau, IMN MacroNano ZIK, D-98693 Ilmenau, Germany
  • [ 7 ] [Zhang, Chenglin]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 8 ] [Fu, Qun]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 9 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 10 ] [Zhao, Chengxi]East China Univ Sci & Technol, Dept Chem, Key Lab Adv Mat, Shanghai 200237, Peoples R China
  • [ 11 ] [Zhao, Chengxi]East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

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Source :

NATURE COMMUNICATIONS

ISSN: 2041-1723

Year: 2018

Volume: 9

1 1 . 8 7 8

JCR@2018

1 4 . 7 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 941

SCOPUS Cited Count: 952

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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