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author:

Li, Quanbao (Li, Quanbao.) [1] | Chen, Chen (Chen, Chen.) [2] | Chen, Zhiwen (Chen, Zhiwen.) [3] | Jiao, Zheng (Jiao, Zheng.) [4] | Wu, Minghong (Wu, Minghong.) [5] (Scholars:吴明红) | Shek, Chan-Hung (Shek, Chan-Hung.) [6] | Wu, C. M. Lawrence (Wu, C. M. Lawrence.) [7] | Lai, Joseph K. L. (Lai, Joseph K. L..) [8]

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SCIE

Abstract:

Results on AI-induced crystallization of amorphous Ge (a-Ge) deposited by vacuum thermal evaporation techniques under thermal annealing in N-2 atmosphere are presented in detail. The a-Ge crystallization and fractal Ge pattern formation on the free surface of annealed Al/Ge bilayer films deposited on single-crystal Si (100) substrates were investigated by using scanning electron microscopy (SEM), X-ray diffraction (XRD), atomic force microscopy (APM), energy dispersive X-ray spectrometry (EDS), and Raman spectra. It is found that the temperature field effects play an extremely crucial role in a-Ge crystallization and fractal Ge formation process. The open branched structure of fractal Ge clusters in Al/Ge bilayer films was effectively prepared by Al-induced crystallization when they were annealed at 400 degrees C for 60 min. These films with fractal Ge clusters exhibit charming noninteger dimensional nanostructures, which differ from those of conventional integer dimensional materials such as one-dimensional nanowires/nanorods, nanotubes, nanobelts/nanoribbons, two-dimensional heterojunctions, thin films, and zero-dimensional nanoparticles. The SEM image shows that a big Al grain was found located near the center of a fractal Ge cluster after the films were annealed at 400 and 500 degrees C for 60 min. This suggests that the grain boundaries of polycrystalline Al films are the initial nucleation sites of a-Ge. It also validates the preferred nucleation theory of a-Ge at triple-point grain boundaries of polycrystalline Al at the interface. This discovery may be explained by the metal-induced nucleation (MIN) mechanism.

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Community:

  • [ 1 ] [Li, Quanbao]Shanghai Univ, Shanghai Appl Radiat Inst, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 2 ] [Chen, Chen]Shanghai Univ, Shanghai Appl Radiat Inst, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 3 ] [Chen, Zhiwen]Shanghai Univ, Shanghai Appl Radiat Inst, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 4 ] [Jiao, Zheng]Shanghai Univ, Shanghai Appl Radiat Inst, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 5 ] [Wu, Minghong]Shanghai Univ, Shanghai Appl Radiat Inst, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 6 ] [Jiao, Zheng]Shanghai Univ, Inst Nanochem & Nanobiol, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 7 ] [Wu, Minghong]Shanghai Univ, Inst Nanochem & Nanobiol, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 8 ] [Chen, Zhiwen]City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon Tong, Hong Kong, Peoples R China
  • [ 9 ] [Shek, Chan-Hung]City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon Tong, Hong Kong, Peoples R China
  • [ 10 ] [Wu, C. M. Lawrence]City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon Tong, Hong Kong, Peoples R China
  • [ 11 ] [Lai, Joseph K. L.]City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon Tong, Hong Kong, Peoples R China

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Source :

INORGANIC CHEMISTRY

ISSN: 0020-1669

Year: 2012

Issue: 15

Volume: 51

Page: 8473-8478

4 . 5 9 3

JCR@2012

4 . 3 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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