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author:

Zhang, Haijiao (Zhang, Haijiao.) [1] | Tao, Haihua (Tao, Haihua.) [2] | Jiang, Yong (Jiang, Yong.) [3] | Jiao, Zheng (Jiao, Zheng.) [4] | Wu, Minghong (Wu, Minghong.) [5] (Scholars:吴明红) | Zhao, Bing (Zhao, Bing.) [6]

Indexed by:

SCIE

Abstract:

A novel ordered mesoporous carbon hybrid composite, CoO/CMK-3, is prepared by an infusing method using Co(NO3)(2)center dot 6H(2)O as the cobalt source. The products are characterized by X-ray diffraction, transmission electron microscopy and N-2 adsorption-desorption analysis techniques. It is observed that the CoO nanoparticles are loaded in the channels of mesoporous carbon. The mesopore structure of CMK-3 is destroyed gradually with increasing of the Coo content. The electrochemical properties of samples as the anode materials for lithium-ion batteries are studied by galvanostatic method. The results show that the CoO/CMK-3 composites have higher reversible capacities (more than 700 mAh g(-1)) and better cycle performance in comparison with the pure mesoporous carbon (CMK-3). Based on the above results, a mechanism is proposed to explain the reason of such a substantial improvement of electrochemical performance in the CoO/CMK-3 composites. (c) 2009 Elsevier B.V. All rights reserved.

Keyword:

Anode materials Cobalt monoxide Lithium-ion batteries Mesoporous carbon

Community:

  • [ 1 ] [Zhang, Haijiao]Shanghai Univ, Sch Environm & Chem Engn, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 2 ] [Tao, Haihua]Shanghai Univ, Sch Environm & Chem Engn, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 3 ] [Jiang, Yong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 4 ] [Jiao, Zheng]Shanghai Univ, Sch Environm & Chem Engn, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 5 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 6 ] [Zhao, Bing]Shanghai Univ, Sch Environm & Chem Engn, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 7 ] [Zhang, Haijiao]Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 8 ] [Jiao, Zheng]Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China

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Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2010

Issue: 9

Volume: 195

Page: 2950-2955

4 . 2 9

JCR@2010

8 . 1 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 96

SCOPUS Cited Count: 96

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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