This　paper　reports　a　facile　solution　route　(water　bath　heating　or　hydrothermal　heating)　for　synthesizing　a　few　Sb-based　self-assembly　structures　including　bundles　of　nanowires,　nanowire-flowers,　long　nanowires,　bundles　of　flakes,　nanobelts,　hollow　prisms.　These　obtained　nanomaterials　were　characterized　by　XRD,　FE-SEM,　TEM,　SAED,　and　HRTEM.　It　was　found　that　the　morphology,　size　and　phase　of　self-assembly　nanostructures　were　strongly　dependent　on　reaction　temperature,　reaction　time.　pH　value,　and　heating　source.　In　particular,　nanowire-flowers　and　hollow　prisms　of　antimony　oxide　or　oxychloride　have　not　been　reported　previously.　A　possible　mechanism　based　on　stepwise　nucleation　and　aggregation　of　nanowires　or　flakes　was　also　proposed.　(C)　2009　Elsevier　B.V.　All　rights　reserved.